Development Of A Society On Wheels Understanding The

Rise Of Automobiledependency In China 1St Ed Junxiu

Wang
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Development Of A Society On Wheels
Understanding The Rise Of
Automobiledependency In China 1St Ed
Junxiu Wang
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Development Of A Society On Wheels
Understanding The Rise Of
Automobiledependency In China 1St Ed
Junxiu Wang

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HOW TO Mix with the van Over Method
Baker and cookbook author Charles van Over developed a mixing work for higher-hydration pizza doughs, which take much longer to mix
method using the speed of food processor blades to ve ry quickly because there isn't enough solid mass for the blades to quite catch the
develop gluten (it was originally developed for bread but works for pizza dough. Instead, the blades move almost as if they were making their way
as well). The overall process is extremely fast: once all the water has been through a puree.)
added, it takes just 45 seconds to complete the mix. The van Over method works in part because it uses the sides of the
Van Over's original method doesn't use a preferment, but that doesn't food processor bowl as well as the lid to "throw• the dough around and
mean that you can't use one. We have successfully mixed doughs with make the actual mixing more efficient. When a wet, loose batter-like
preferments using this method, and a preferment can add flavor. Mixing dough is in the processor, however, it doesn't quite form the strong
a dough for just 45 seconds, however, seems opposed, at least in spirit, to mass that's needed for it to be thrown around the bowl, which is what
the time and patience a preferment requires to ripen. The food processor happens with stiffer doughs. Additionally, the speed of the blades
recipes in the Pizza Dough Recipes chapter will fit in a standard food pro­ cutting through the dough and mixing in air would cause the dough to
cessor bowl, but they can be scaled up for larger quantities (see page 1). oxidize quickly.
Although this method has its limitations, we acknowledge that a Because the friction created inside the food processor bowl heats up
dough mixed in 45 seconds is remarkable and worthy of including; it the dough considerably, water temperature is crucial here; this is one of
may be suited for specific environments and purposes (home baking , the rare circumstances where nonindustrial pizza makers should take the
some restaurants, and even large-scale industrial bakeries). The crust it time to calculate the water temperature. This precaution may still leave
produces is attractive, but the crumb can be tight. (This method doesn't your dough considerably warmer than those mixed in other ways.

1 Combine all the dry ingredients in the food

processor bowl.
2 Turn the processor on, then pour in all the
water in a steady stream.
4 If the gluten is not fully developed (it won't
hold a windowpane; see page 2:30), then
alternate between processing for 5 s and

To use the van Over method with a preferment,

3 Process for 45 s. testing the gluten development, until you
reach full gluten development.
you'll need to add it to the food processor bowl first,
along with the flour and salt. Pour the water in while
the machine is running. Stop once the dough has
formed a ball and check to ensure that it has been
mixed to full gluten development by performing the
windowpane test.

HOW TO Mix Using the Double Hydration Mixing Method

Highly hydrated doughs, such as focaccia, take a long time to develop in bowl. This issue can be remedied by adding the water to the mixer in two
a machine. The generous amount of water makes it difficult for the hook steps rather than al I at once.
on the mixer to catch the dough well, and it instead sloshes around in the

1 Add 90%-95% of the water to the mixer's

bowl.
3 Allow your dough to autolyse for 30 min. 4 Turn the machine to low speed. Pour the
Meanwhile, stir the salt into the remaining salt solution in a steady stream as the
water. machine mixes.
2 Add the remaining ingredients (except the
salt and remaining water) and mix on low
speed until you achieve a homogeneous
5 Mix to medium gluten development. Trans­
fer to a lightly oiled plastic tub or bowl to
mass. bulk ferment.

HOW TO Incorporate Inclusions by Machine

Using a mixer is dramatically faster than mixing by hand but requires Be careful to mix on the lowest speed to minimize damage. Mix until the
some care when incorporating inclusions into a dough. The solid matter inclusions are incorporated into the dough; they will be enveloped in the
(your inclusion) is t rying to bond with the dough; this can stress the dough, not just hanging on to it.
dough's strength and integrity as the inclusions pull and push through it.

1 Mix the dough to medium gluten

development.
3 Mix on low speed for 1-2 min, just until the
inclusions are evenly distributed through­
4 Transfer the dough to a lightly oiled tub and
finish developing the gluten throughout
out the dough and are completely bulk fermentation by performing a series of
2 Stop the machine and add all of the
inclusions.
enveloped. four-edge folds (see page 17) until it reaches
full gluten development.

MAKING PIZZA DOUGH 13

HOW TO Make Compleat Wheat Dough
We developed this method to produce what is technically a 100 � whole almonds. This toasting also renders useless the enzymes that hinder
wheat dough without the dense, gummy texture you often get from gluten development. And because bran and germ are notorious water
whole wheat flour. This allows for whole wheat flavor without the vol­ thieves (they suck water away from the dough and hold on to it, part of
ume-killing effects of the bran and germ. the reason why whole wheat doughs feel dense), we presoak them so
To make whole wheat flour, commercial mills grind the wheat to a fine they will have already absorbed all the water they need before being
powder and then remove the bran and germ, which is the same process mixed into the dough.
used to make white flour. The separated germ is toasted since its oils In the various compleat wheat recipes on pages 82-85, we have calcu­
can become rancid and then spoil the flour. The bran and germ are then lated how much bran and germ each recipe needs in order to mimic the
mixed back into the white flour. Our method also involves using white percentages found in whole wheat flour. We opt to add the soaked and
flour and introducing the bran and germ back in when the dough is half­ toasted bran and germ to the flour used in the master recipe. This will
way developed (medium gluten development) to get the flavor benefits result in the highest possible volume and also the most flavorful whole
without the dense texture. wheat crust you've tasted.
Beyond that, we toast the bran and germ to make them more flavor­
ful and aromatic. It's like the difference between eating raw and toasted

1 Toast the bran and germ in an even layer at 3 Combine all of the dough ingredients 6 Transfer to a lightly oiled tub and finish
175° C / 350 ° F in a home or deck oven. Do except for the soaked/toasted bran and developing the gluten throughout bulk
not use a forced fan because it will blow the germ and mix to medium gluten fermentation by performing a series of
bran and germ off the sheet pan. Toast until development. four-edge folds until the dough reaches full
aromatic, 5-7 min. Cool completely. gluten development.
4 With the machine stopped, add all of the
2 Mix with the water, and soak for at least
10 min (or up to 24 h).
soaked/toasted bran and germ.

5 Mix on low speed for 1-2 min, just until the

bran and germ are evenly distributed and
are completely enveloped by the dough.

Your Daily Pizza

Modern lifestyles don't always make it easy to produce our proverbial improvements while keeping the low-maintenance schedule (see recipes
daily bread or, in this case, daily pizza. We were inspired by an on page 92). We add around 0.2200 ascorbic acid to strengthen the
undemanding daily baking routine created by Jeff Hertzberg and Zoe dough's gluten network and reduce oxidation, which eventually would
Franryois. Starting with 2007's Artisan Bread in Five Minutes a Day, make the dough turn gray in the refrigerator. Polydextrose is included in
Hertzberg and Franryois showcased a make-ahead bread technique that our Neapolitan variation to produce a very crispy crust.
became the centerpiece of a best-selling series of cookbooks. They If you have made your first large batch of dough, you can harvest a
demonstrated how a large batch of dough for almost any type of bread 500 g / 1.1 lb (or 1 kg / 2.2 lb) piece, divide it (if necessary), preshape
can be stored long-term in the refrigerator, with the baker harvesting a and shape it, and then proof it. Accounting for proofing time, the recipe
loafs worth of dough every day for up to two weeks. takes more than S minutes of effort per day, but with some preplanning
Hertzberg and Franryois have refined their methods over time, this method supplies daily pizza with a fraction of the work.
and we have modified their recipe to make pizza dough with our own

HOW TO Make Your Daily Pizza

1 Combine all of the ingredients in the mix­ 3 Divide the dough as instructed in the mas­
ter recipe.
5 Proof for 4 ½-5½ h at 21° C / 70 ° F, covered.
If you are making Neapolitan pizza dough,
er's bowl. Mix on low speed using a paddle
or hook attachment to a homogeneous proof for 3-4 h at 21° C / 70 ° F, covered.
mass, 2-3 min. Transfer to a lightly oiled tub 4 Proceed with the preshaping and shaping Proceed with the shaping and baking
and cover. instructions (if applicable) in the master instructions in the master recipe.
recipe.
2 Bulk ferment for 1 h at 21 ° C / 70 ° F. Remove
the lid and put a piece of plastic wrap
directly on the surface of the dough to
cover it completely. Refrigerate for at least
23 h before your first bake.

14 VOLUME 4: KITCHEN MANUAL

FACTORS THAT AFFECT MIXING TIME
The following table details factors that may affect mixing time and, therefore, your dough. Suggestions for eliminating (or minimizing) any negative effects
on your dough are also noted.
Factor How it can affect your dough How to keep it from affecting your dough
dough temperature if the dough is too cold when it comes out of the for cold dough, adapt your schedule to compensate for
mixer, it will take longer to ferment than a dough that the difference in fermenting time; to fix hot dough, put
comes out at our recommended range of 24-25 ° C / it on a floured sheet pan or in a large tub, and use your
75-78 ° F; a dough that comes out too hot (generally hands to flatten it as much as possible; cover it with
27° C / 80° F and above) will hydrate faster and there­ plastic wrap sheet (or a clean plastic bag), and refrig­
fore proof faster, which will affect its flavor and make erate it for at least 10-15 min or until the dough has
it harder to handle; warmer doughs are desirable in reached the recommended temperature range
some cases, such as our Neapolitan pizza dough with
poolish and our master Neapolitan pizza dough
amount of dough in the mixer too much dough will take longer to mix and increase know the capacity of your mixer and don't overload or
mixer friction, and too little won't mix well or at all underload it; for more on mixer capacity, see page 12
type of flour some flours, such as whole wheat, contain bran, which understand how each flour is used for different pur­
can rip the dough; stronger flours take longer to mix; poses, and choose the flour that's best for the dough
low-gluten flours mix quickly and can break down you want to make
just as fast; rye flours, in addition to being low gluten,
absorb more water than regular wheat flours
amount of water high-hydration doughs take a long time to mix; low­ for high-hydration doughs, use the double hydration
hydration doughs are hard to mix because they're method (see page 13); for dry, stiff doughs, mix on the
stiff and can bog down the machine lowest speed and/or use a paddle attachment instead
of a hook
fats fats slow down gluten formation and interfere with the when possible, add high-fat ingredients after the
bonds that keep gluten together, by coating them and dough has reached at least low gluten development
preventing them from hydrating
inclusions as with bran, solid inclusions such as nuts and fruit add solid inclusions after the dough has reached
can rip the dough medium gluten development (see page 2:30)

MAKING PIZZA DOUGH 1S

HOW TO Mix in a Bowl
This is our preferred method for mixing a dough by hand. This is the most hands. Spoons or spatulas can't get into the dough as well to distribute
basic method for mixing dough: it involves using only a bowl and your the ingredients evenly.

1 Combine the water and yeast in a bowl.

Whisk to dissolve the yeast. If you're using
4 Turn the dough onto a wooden or marble
worktable (scrape the bowl clean with a
6 Transfer the dough to the tub and immedi­
ately perform a four-edge fold in it.
a preferment, dissolve it in the water. bench scraper). Knead the dough with
both hands until you reach medium gluten 7 Rest the dough for 30 min and perform the

2 Pour the flour and salt on top of the water

and yeast mixture, and begin to stir with
development (perform the windowpane second four-edge fold; repeat this step

test to make sure; see page2:30). If you until the dough reaches full gluten devel­
your fingertips, then with your hands. opment. Perform the windowpane test
wish to, you can mix to full gluten develop­
ment by hand and skip to step 8. (see page2:30) to make sure.
3 Mix until you achieve a shaggy mass.

5 Clean your hands well, scraping off the 8 Rest the dough for20-30 min after the last
fold before dividing.
excess dough with the bench scraper.
Lightly oil a rectangular or square plastic
tub.
A ripe preferment will float in the water. For more
on preferments, see page l :301. Typically with this method, you'll have to bulk fer­
ment for 2-2½ hours and perform a total of four to
seven four-edge folds at 30-minute intervals.

HOW TO Mix with the No-Knead Method

Jim Lahey, renowned baker and cookbook author, popularized this "no-knead" isn't entirely true; there's some manipulation involved, but
revolutionary technique. It reinforces the idea that when ingredients the handling is much less than a typical dough requires. This dough relies
are combined and left alone, they'll do what's in their nature and pro­ on time-and the pizza maker's patience-to do the work that your hands
duce a great pizza (see the recipes on page90). Calling this technique would usually tackle.

1 Combine the ingredients in a bowl and mix

by hand to a homogeneous mass. Transfer
3 Divide and preshape the dough as
instructed in the master recipe.
5 Proceed with the shaping and baking
instructions in the master recipe. If you are
to a lightly oiled tub, and cover. making New York pizza dough, proof for
4 Proof for 3-4 h at21 ° C /70 ° F, covered. ° °
4½-51/2 h at21 c/70 F.
2
° °
Bulk ferment for12-18 h at21 C /70 F. Optional: After preshaping, you can also
cold-proof this dough at 4 ° C /39 ° F for 1-2
d for even better baking results. If you cold­
proof the dough, remove it from refrigera­
We don't recommend this method for our pan­
tion 1½-2 h before baking so it warms up
baked pizzas since the dough doesn't get as strong as
and is easier to stretch out.
we like. We had to degas it too much in order to get
the dough to fill the pan.

16 VOLUME 4: KITCHEN MANUAL

STRATEGIES FOR BULK FERMENTATION
Type of mix Length of bulk Number of four-edge folds Recommended doughs Doughs not recommended
fermentation (unless noted in the recipe)
medium gluten develop­ 2-2½h 4-6 focaccia dough thin-crust pizza dough
ment New York square pizza Brazilian thin-crust pizza
dough dough
high-hydration al taglio deep-dish pizza dough
pizza dough Neapolitan pizza dough
all doughs with inclusions New York pizza dough
artisan pizza dough
Detroit-style pizza dough
full gluten development the dough is bench 0 thin-crust pizza dough New York square pizza
rested instead for Brazilian thin-crust pizza dough
15-20 min before dividing dough high-hydration al taglio
deep-dish pizza dough pizza dough
Neapolitan pizza dough foccacia dough
New York pizza dough
artisan pizza dough
Detroit-style pizza dough

HOW TO Perform a Four-Edge Fold

This is a crucial technique to master. Executing it properly will give the organized pattern, and it improves fermentation by evening out the tem­
dough structure to hold its shape and expand evenly in the oven. Proper perature of the dough.
folding strengthens the dough and helps give the gluten network an

1 Transfer the mixed dough to a lightly oiled

4 Pull the left side of the dough up and over
6 Lift up the end that's farthest from you, and
plastic tub, perform a four-edge fold, and to the right side of the tub. then pull it toward you. Some bakers then
cover it with an airtight lid. flip the dough over so that the seam is
5 Lift up the end that is closest to you, and underneath. If you are working with a drier
2 Lightly moisten your hands or coat them
with a thin layer of oil to prevent the dough
then fold it away from you so that it meets
the end of the dough that's farthest from
dough, seal the seam to create a more
uniform shape, since it lacks the moisture
from sticking. you. content needed for this to occur naturally.

3 Pull up the right side of the dough and fold

it over to the left side of the tub. 7 Place the lid on the tub, and continue to
bulk ferment.

MAKING PIZZA DOUGH 17

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Ionic Mobilities

Such grids, connected to a high-frequency oscillator, were initially

designed by the author as electron filters to capture electrons trav-
ersing them in a field normal to their plane, while permitting the
more sluggish ions to pass through (10). It occurred to Bradbury
to use the filters as electrical shutters for electrons. If the period
of the high frequency, and its amplitude relative to the impressed
driving field pulling electrons or ions through the gauzes are properly
chosen, then the gauze will act as a shutter. Thus, except for a
very short interval during each half cycle when the field between
alternate wires of the gauze is zero, no ions or electrons will get
through. Hence, the shutters which lie in equipotential planes
in the field and which have zero potential between wires of the
grid at the time they are open, open and close in synchronism
through a master oscillator. Before and after the point of zero field,
the horizontal fields between wires in the plane of the grid cause
the electrons or ions to have lateral motions which usually lead
to capture on the wires. The transverse fields will also influence
electrons or ions which get through by imposing transverse oscil-
lations on them for distances of several wire spacings above and
below the gauze. In this fashion, the grids can somewhat alter the
energy of the electrons in the field. If the distance d between the

12

10

H2
8

300 400 500

V

Fig. 1.12. Current-potential curves in the Bradbury-Nielsen electrical

shutter method for electrons in H 2 . Note the diminishing amplitude of the
peaks as s u c c e s s i v e orders pass through.
24 T h e B r a d b u r y - N i e l s e n Shutter Method

§7

planes of the two grids is large compared to the wire spacing, the
disturbing effect of oscillations on the mobilities will be small.
Thus, "interpénétration" or gauze effects will be at a minimum.
Symmetry of grid action reduces errors still further. By varying
the frequency of the a.c. on the grid, or the imposed field X between
A and 6 , the carriers, electrons, or ions, leaving the lower grid
G during phases of zero field, will pass through grid G ' i f they trav-
erse the space d between the gauzes in T/2, 2T/2, 3 T / 2 seconds.
Here T - 1 /N is the period of the potential of high frequency /V.
In figure 1.12 is shown a typical curve for electrons in H2 as V,
the potential between A and B increases. The distance d between
grids was 5.93 cm. The grids were number 40 copper wires spaced
1 mm apart. The system used was all glass except for the mica
grid frames. Because of the mica the chamber could be baked out only
to 300° C. The high frequency used in the observations shown was
2.205x106 cycles/sec, with a potential between the grid wires of 40
volts. The pressure was 6.8 mm, and peaks were observed at 390, 119,
and 62 volts. These were electrons that crossed in 1/2, 2 / 2 , and 3 / 2
of a cycle. The velocities were 26.5, 13.2, and 8 . 8 4 x 1 0 5 cm/sec.
Since the velocity of electrons getting across in 1/2 cycle was about
three times that for electrons getting across in 3 / 2 cycles, the shutters
were effectively open, as regards current transmittal, at least three
times as long as for the slower ones. Since this effect occurred for two
shutters, the toted current as a function of potential was markedly
greater for the fast than for the slow ones. Diffusion of the electrons
is also responsible for some of the attenuation observed. The loca-
tion of the peaks is possible to within 2% for carriers of unique
mobility. The method is satisfactory for such carriers.
The operation of the shutters is open to theoretical calculation
for carriers of unique velocities, and comparison between calculated
and observed curves given by Bradbury and Nielsen for the case
above is shown in figure 1.13. It is seen that the resolution is not
so good as that of the Tyndall-Powell four-gauze method. If there
is any doubt as to the absolute values yielded by the method, d
could be varied for constant X and the values of T/2 corresponding
to the same order of peak could be determined. This would eliminate
any gauze errors. The mobility is given by k = 2d^/V0T, with T
the whole period. It has not been tried on ions, but there is no a priori
reason why it should not work. It may be possible that some of the
microwave or radar-pulsing techniques could be applied to this in
some ranges. Thus, if the grids were biased with a fixed field, to be
closed except when a neutralizing square wave pulse of short duration
25 Ionic M o b i l i t i e s

§8

F i g . 1.13. Comparison of observed and calculated current-potential curves

with the Bradbury-Nielsen shutter method, using L o e b electron filters a s
shutters. Note the rather broad peaks and poor resolution.

is applied at a constant-repeat frequency, it is possible that better

results could be obtained, since distance d, and field -Y can be con-
veniently measured. This system has the advantage over the four-gauze
method of being somewhat more simple mechanically, except for the
•mica mounting of the grids, which can now no doubt be replaced by a
heat-resistant insulator.

§ 8 . The Townsend Magnetic-Deflection Method (9).

This method evaluates mobility by directly comparing the magnetic
26 T h e T o w n s a n d M a g n e t i c - D e f l e c t i o n Method

§8

and electric deflections of a beam of electrons or ions of unique

sign in crossed fields. So long as the electrons or ions move in
a beam with a uniform drift velocity v = kX, a uniform magnetic
field H of appropriate magnitude transverse to the motion will cause
a deflection at right angles both to H and to v; i . e . , to the electri-
cal field X causing v. The tangent of the angle 6 of the small de-
flection can be measured. It is directly proportional to the ratio
of the transverse magnetic force Hev = HekX and the driving electrical
force Xe in the beam direction. In this c a s e the ions or electrons
are only initially accelerated, for in the gas they reach a steady-
state drift velocity.
Townsend accomplished the measurement by a simple and direct
method. Using electrons from a hot filament F in figure 1.14 and
a longitudinal s l i t S normal to the plane of the figure in the plate
B opposite F, a stream of electrons traverses the equipotential
drift space of length d to a group of three electrodes whose axes
are parallel to slit S. The center section C2 of the electrode directly
opposite slit S is of width a and is placed between the center of
the s l i t s isolating C^ from electrodes Cj and C3, of equal width.
All three electrodes can be connected in turn to an electrometer.
The whole system, with equipotential vanes, can be outgassed and
placed in a uniform magnetic field, either from a Helmholtz coil
or between the pole p i e c e s of a magnet. The beam of the carriers
passing through S will traverse d in the absence of a magnetic field
H as an undeflected beam striking C 2 . Except for lateral spreading
of the carrier by diffusion, the beam will all be caught on electrode
C 2 . The transverse magnetic field H is switched on and adjusted
to Hi first, so that the current is evenly divided between electrodes
Cj and C 2 , Hj being retorded. Then H is reversed and readjusted
to # 2 . so that the beam splits evenly between C 2 and Q , and // 2
is recorded. Calling H = (H\ + Hz)/2, it follows at once that tan 0'=.d =
a/Id = fa/f0 = Hev/Xe, with fa and fo the forces along the magnetic
and electrical fields. Thus the velocity v is given by v = Xa/Hld,
and the mobility k is given by k = a/2dH. For electrons, Townsend
observed that k was a function of X and p, or better X/p, so that
there i s , properly speaking, no sense to the term " m o b i l i t y . " The
method i s , therefore, ideally suited to the study of the variation
of k with X/p, s i n c e X does not enter explicitly into the expression
for k. It does enter into measurement in that it determines the value
of v and hence the values of fields H needed, thus placing physical
limits on the range of values of X/p and p that can be used. It is
capable of giving average velocities only, and its resolving power
is very poor.
Ionic Mobilities

Fig. 1 . 1 4 . Diagram of the apparatus used in the Townsend

magnetic-deflection method.

Regarding the mobility k, this i s given, at l e a s t in theory, for

ions at low fields and constant temperature, by k = K 760/p, with
K the reduced mobility. P l a c i n g this in the relation deduced y i e l d s
K = (p/760) {a/2dH). For use with values of K, expressed in cm/sec
per volt/cm, K must be divided by 10 8 , since it i s given in terms
of e.m.u. through the use of H. From this relation may be derived
the limits of pressure over which the method can be used in any
given situation in terms of the permissible values of K and H. In
most applications the values of a/2 range around 0.5 cm and d about
10 cm. Thus p = 3 . 0 4 x l 0 ~ 4 KH. For ions where K i s of the order
of 2, it i s seen that p = 6.08xlO"" 4 B, and that to work at appreciable
pressures, H must be large, uniform, and constant over a large volume,
of about 1 5 x 1 5 x 1 5 cm. Thus A. V. Hershey (9) had to use values
PALGRAVE STUDIES IN
SPORT AND POLITICS

Football and
National Identity
in Twentieth-
Century Argentina
La Nuestra
Mark Orton
 Palgrave Studies in Sport and Politics

Series Editor
Martin Polley, International Centre for Sports History and Culture
De Montfort University, Leicester, Leicestershire, UK
Palgrave Studies in Sport and Politics aims to nurture new research, both
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the law, and many other forms of politics. It includes approaches from a
range of disciplines, and promotes work by new and established scholars
from around the world.
 Mark Orton

Football and National

Identity
in Twentieth-Century
Argentina
La Nuestra
Mark Orton
Newport, UK

ISSN 2365-998X ISSN 2365-9998 (electronic)

Palgrave Studies in Sport and Politics
ISBN 978-3-031-20588-0 ISBN 978-3-031-20589-7 (eBook)
[Link]

© The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer
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About the Editors

Dr. Deepmoni Deka is working as Technical Officer Gr-I in Centre for the Environ-
ment at Indian Institute of Technology Guwahati, India. She completed her postgrad-
uation in Molecular Biology and Biotechnology from Tezpur University and Ph.D. in
Environment from Indian Institute of Technology Guwahati. Her research interests
include bioremediation of environmental pollutants from soil and water, monitoring
of ground and surface water quality, nutrient quality, determination of NPK content
in soil, purification and characterization of industrial microbial enzymes, bioethanol
production using waste biomass, resource recovery, waste valorization, biopolymer
based hydrogel. She has 15 research publications in peer reviewed journals, 1 book
chapter and more than 25 conference papers. Presently, she is working in the field
of biobased plastic production using waste, wastewater treatment specifically phar-
maceuticals, dye and heavy metal removal, biopolymer based hydrogel for sensing
of pollutants and drugs.

Dr. Subrata Kumar Majumder is a Professor in Chemical Engineering Depart-

ment at Indian Institute of Technology Guwahati, India. He completed his Ph.D. in
Chemical Engineering from Indian Institute of Technology Kharagpur. His research
interests include Process Intensification in Chemical Processes, Intensification in
environmental process system, Micro-nano bubble science and technology and
its applications, Microchannel-based and Jet driven gas-aided extraction, Mineral
Beneficiation, Enhanced Oil Recovery by Micro-nanobubble, Multiphase Flow and
Reactor Development. He is a Life Fellow of Council of Engineering and Tech-
nology (India), Life Fellow of Indian Institute of Chemical Engineers and Fellow of
the International Society for Research and Development, London. He is a recipient of
various honours and awards like: Editor, Journal of Chemical Engineering Research
Studies, Guest editor, American Journal of Fluid Dynamics, published by Scientific
and Academic Publishing Co., USA, Editorial board member of Scientific Journal
of Materials Science, IIME Award on beneficiation from Indian Institute of Mineral
Engineers (IIME), Editorial board Member of the Journal of Science and Technology,
Scientific and Academic Publishing, USA, Advisory board member of Excelling
Tech Publishers (ETP), London, UK., life member of Indian Institute of Mineral

xxix
xxx About the Editors

Engineers, member of Institute of Engineers (India), Member of Asia-Pacific Chem-

ical, Biological and Environmental Engineering Society (PCBEE), senior member
of International Association of Engineers (IAE), Japan. He authored four books,
five book chapters, has 76 conference papers and has more than 100 publications
in several reputed international journals. He has completed several sponsored and
consultancy projects. He has a collaboration with the Aalborg University, Denmark
and University of Los Andes, Colombia, Curtin University, Australia, Edith Cowan
University, Australia. Presently he is working in the field of Microbubble science and
technology and its applications in mineral beneficiation, industrial effluent treatment,
and arsenic, ammonia and dye removal and process intensifications in chemical and
mineral processing.

Dr. Mihir Kumar Purkait is a Professor in the Department of Chemical Engineering

at Indian Institute of Technology Guwahati (IITG). Prior to joining as faculty in IITG
(2004), he has received his Ph.D. and [Link]. in Chemical Engineering from Indian
Institute of Technology, Kharagpur (IITKGP) after completing his [Link]. and [Link].
(Hons.) in Chemistry from University of Calcutta. His current research activities are
focused in four distinct areas viz. (i) advanced separation technologies, (ii) waste to
energy, (iii) smart materials for various applications and (iv) process intensification.
In each of the area, his goal is to synthesis stimuli responsive materials and to develop
a more fundamental understanding of the factors governing the performance of the
(c^12,500, h-index = 64, 10 index = 150). He has authored 10 books in CRC press
and Elsevier in last 5 years.
Water Quality and Wastewater Treatment
Multi-metal Adsorption and Cyclic
Desorption Characteristics of Zn+2
and Cu+2 Constituting Multi-component
Synthetic Wastewater System Using
Commercial Resins

Prabhat Kumar Patel , Lalit Mohan Pandey ,

and Ramagopal Uppaluri

1 Introduction

The incessant release of household, industrial, and agriculture wastes into water-
bodies translates into irreversible pollution of water bodies. Among them, heavy
metals constitute a substantial class and have a potential role to jeopardize human
health (due to their carcinogenic status and bio-accumulating proclivity) through the
human food chain. Unlike most organic pollutants, heavy metals cannot be elimi-
nated through biological decay. Thereby, their non-biodegradable status in the envi-
ronment accounts for greater toxicity for the living beings and catalyzes critical need
to remove them from the ecosystem and sustain human and biological species health
and harmonious co-existence [17]. Further, good quality water is becoming scarce on
a day-to-day basis, and henceforth, it is important to reuse wastewater bodies being
generated through mining and industrial operations and colonized municipalities.
The removal of hazardous heavy metals (iron, copper, lead, chromium, zinc, etc.)
from effluents is very difficult owing to the many obstacles. Both conventional
and novel separation schemes exist for the resolution of such stiff prepositions.
Notable processes among these are membrane separators, ion exchangers, electro-
chemical reducers, leaching and adsorption processes [21], chemical precipitators,

P. K. Patel
Centre for the Environment, Indian Institute of Technology Guwahati, Guwahati, Assam, India
e-mail: prabhat18@[Link]
L. M. Pandey
Department of Biosciences and Bioengineering, Indian Institute of Technology Guwahati,
Guwahati, Assam, India
e-mail: lalitpandey@[Link]
R. Uppaluri (B)
Department of Chemical Engineering, Indian Institute of Technology Guwahati, Guwahati,
Assam, India
e-mail: ramgopalu@[Link]

© The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. 2023 3
D. Deka et al. (eds.), Sustainable Environment,
[Link]
4 P. K. Patel et al.

coagulators and flocculators, biosorbers, electro-kinetic processes, nanoparticle-

assisted processes, and foam fractionators. These can be formally classified into
three categories, namely schemes involving greater usage of chemical media, sorp-
tive approaches, and biomaterials and processes [24]. Environmental sustainability,
cost-effectiveness, long-term adsorbent performance by withstanding cyclic adsorp-
tion–desorption processes, and acceptable recovery are few targets being targeted for
the identification of potential separation schemes for industrial-scale operations [14].
Multiple heavy metal containing wastewater streams (with Cu, Zn, Pb, and Fe) can
be characterized to be with lower metal concentrations. For such systems, chelating
and ion exchange resins that follow the combined principles of physisorption and
chemisorption are highly promising. With alternate ligands made of either hydroxyl
or sulfonic acid or aminomethyl phosphonic acid or nitrogen, many commercial
ions exchange resins possess greater affinity to reversibly bind multiple metal ions
and thereby pave the way for the mitigation of heavy metal content in the water
bodies. Till date, numerous investigations affirmed the promising performance of
many such resins having sulfonic acid functional group (Amberlite IR 120H [7],
Dowex 50 W [18], Purolite C100 [1], Dowex HCR S/S [2], Lewatit SP 112 [8],
Dowex marathon C [22], Amberjet 1200H, Amberlite IRN97H [20]), iminodiacetic
acid functional group (Amberlite IRC748, Amberlite NDC 702 [11], styrene DVB
copolymer [12], GMA/DVB magnetic resin [4], Lewatit TP208 [15], Lewatit TP
207 [8]), aminomethyl phosphonic acid functional group (Lewatit TP 260 [15,
8]), carboxylic functional group (Amberlite IRA 400 [3], Lewatit CNP 80 [23],
Carboxyphenyl resorcinarene-impregnated Amberlite XAD-4 [26]), phenolic func-
tional group (Modified quebracho tannin resin [25]), tetrazolyl functional group
(Polyvinyltetrazole grafted PS resins [6], N-methyl glucamine functional group
(Amberlite IRA 743 [15]), and amine functional group (Aminated resin via SI-ATRP
[16]).
In the above-cited investigations, most researchers targeted simple aqueous solu-
tions being prepared with either one or two heavy metals. Very few prior art
targeted about and more than 4 heavy metal containing solutions [6, 10–12]. Thus,
it is apparent that for simpler solutions, close to 100% desorption efficiency may
have been reported which is bound to reduce significantly for complex solutions
containing 4–6 heavy metal ions along with other ions and additives. Indicating such
reduction in the desorption efficiency, [12] considered Styrene–DVB copolymer ion
exchange resin (having Iminodiacetic acid functional group) and four heavy metal
ion containing solutions but inferred lower desorption efficiencies of 0%, 45%, 70%,
and 65% for Cd, Pb, Ni, and Cr, respectively.
Thus, it is important to identify a complex simulation wastewater system that
possesses 4–6 heavy metals along with other precursors [5]. Thereby, depending upon
the solution complexity, HSAB theory needs to be considered for the identification
of relevant commercial ion exchange resins and thereby carry out adsorption and
desorption studies. Considering such conceptual methodology, two solutions have
been identified based on the available wastewater stream data in the available prior art
and refer to Cu+2 and Zn+2 dominating solutions being generated from agricultural
waste and mining industry [13]. Thereby, according to HSAB theory, Amberlite IR
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