Venting of atmospheric and low-pressure

storage tanks - ISO 28300

PROTEGO® Safety Seminar in Jakarta

21st of September, 2012

Selamat Datang
presented by:
Gostombang Pardede – PT Karya Nireko Warga Nusa
Wolfgang Kichner – Protego Germany
Dr. Thomas Hembach – Protego China

1
 Agenda: ISO 28300 – Venting of Tanks

· Background of the development

· Venting requirement
caused by pumping and thermal effects
· How to consider insulation
· Emergency Venting

2
 Development of API 2000 6th ed.

ISO 28300
API 2000
Petroleum, petrochemical EN 14015
5th edition and natural gas industries
Annex L
– Venting of atmospheric
and low-pressure storage
tanks
TRbF 20

API 2000
6th edition

3
Background and development of ISO 28300 Standard

• ISO 28300 was mainly developed based on the API 2000

5th Edition standard 1998 and the EN 14015 Standard
Annex L and the German TRbF 20
• Contradiction towards the venting requirements for normal
venting
• Contradiction towards the use of vents as flame arresters

Committee goal:
• This standard shall consider all state of the art knowledge
concerning tank venting and safety and provide best
practice to the user

4
Why new calculation methods for determining normal
venting requirements?

• Prof. Salatino from the University of Napoli predicted that

the calculation method of API 2000 5th may underpredict
thermal breathing
• The German TRbF 20 standard developed by Dr. Hans
Foerster from the Federal Institute if Physiks (PTB) also
results in higher values for thermal breathing
• The EN 14015 Standard developed by Dr. Wheyl from
BASF also results in higher breathing values

All the above methods depend on a detailed

thermodynamic model and provide higher inbreathing
rates than the API 2000 5th ed. standard

5
Real incidents were motivation for further research

6
Validation of results for inbreathing

Prof. Salatinos‘ Model calculation at University of

Napoli, 1999

• Tank: V = 63000 m3; D = 70 m; H = 15 m

• Δ T = 40 °C
• Water (rain) flow density
• Refined model calculation
- Dynamic simulation (pressure differential at vent)
- Different start temperatures of roof, shell
and product

7
 Validation of results for inbreathing

Prof. Salatino Model calculation at University of Napoli, 1999

8
Validation of results for inbreathing

Life field tests and model calculation

at Hoechst in 1980 and 1981
• Tank: V = 617 m3; D = 8,5 m; H = 10,6 m
• 17 °C ≤ Δ T ≤ 26 °C
• Water (rain) flow density: about 60 kg/m2h
• TRbF-model calculation

9
Validation of results for inbreathing

10
Summary

• The new section is based on the European EN 14015 Standard.

• The approach used is more general than API (the API approach
is centered around hexane or similar services).
• Calculated vent rates with the new approach can be substantially
higher for certain tank sizes than what is shown in API-2000.
• A research paper from Prof. Salatino and research results from
Hoechst in Frankfurt, which had been provided by Dr. Hans
Foerster from the PTB justified this change.
• An advantage of the new calculation method is that it does allow
to consider full and partial insulation of the tank for normal in- and
out-breathing.

11
Storage Tanks have to breath

Pump in…. Pump out….

Heating Up… Cooling Down…

12
ISO 28300 venting requirements

Normal out-breathing and normal inbreathing flows are

defined as the combination of tank vent flows due to:
n Liquid flows into and out of the tank

n Ambient weather (thermal) effects

& =V
V & + &
V
out thermal- out pump - in

& =V
V & + &
V
in thermal-in pump - out

13
Basis: Model calculations for a fixed roof above ground
storage tank of steel

General assumptions and approximations:

• Uniform (time dependent) temperatures of wall, tank

atmosphere, ambient air and rainwater-film
• Primary result is the temperature of the tank atmosphere
in dependence on time ; volume flow rates are then
deduced by an isobaric approach (constant ratio of
volume to temperature)
• Tank atmosphere is air at ambient pressure
• Wall thickness is according to common tank standards ( ≥
4 mm)
• No heat flux via tank bottom

14
Determining of normal & emergency venting requirements

General Basic Equation for ISO 28300 Model:

& V dTg
V = ×
Tg dt
Energy balance to describe temperature
distribution with respect to time

dTg
Q = k × A × (Tg - Ts ) = V × r g × c g ×
&
dt

15
Heat flows during heating by solar radiation
(outbreathing)

solar irradiation
far IR radiation loss

convection convection

16
Tank breathing from Solar Radiation:

dT
Ts : e × q& a - a u × (Ts - Tu ) - a g × (Ts - Tg ) = s × r s × cs × s
dt
1 2 3 4

V dTg
Tg : a g (Ts - Tg ) = × r g × c g ×
A dt
5

1: heat input from sun radiation to wall of tank

2: heat transfer from wall to environment
3: heat transfer from wall to gas in tank (coupling term)
4: temperature change of tank wall over time
5: temperature change of gas in the tank

17
Parameters and conditions for outbreathing

Solar radiation
• Radiation flow density 1 kW/m2 ; Absorption capacity ε = 0,6;
• Start : step function

Radiation loss
• Radiation flow density 80 W/m2 ; Emission capacity θ = 0,6

Start temperatures
• Wall, tank atmosphere and ambient air: 15°C

Heat transfer coefficients

• wall > ambient air 2 W/m2K;
• wall > tank atmosphere 2 W/m2K

18
 Solution if solving differential equation:
80

Maximum volume flow JW

30

JG
60
Volume Flow V in m3/h

Temperature J in oC
25

40
VG,B

20
20
Maximum volume flow occurs
at maximum delta T

0 15
0 900 1800 2700 3600 4500 5400 6300 7200
Time t in s
19
Thermal out-breathing simplified as in ISO 28300

&
V = C V 0,9
R in
thermal- out out T

Cout = 0,2 latitude : > 58°

Cout = 0,25 latitude : 58°-42°
Cout = 0,32 latitude : < 42°

Rin = reduction factor insulation

Vt = tank volume

20
Comparison – out-breathing

10000
volume flow [m³/h]

1000

100

3180 m³
10
100 1000 10000 100000
tank volume [m³]
TRbF H/D=0,5 TRbF H/D=1,5 TRbF H/D=2
API H/D=0,5 API H/D=1,5 API H/D=2
ISO / EN 42°-58°

21
 Heat flows during cooling by rain (inbreathing)

Rain water flow to wall

conduction

convection convection
and
evaporation

Rain water drain from wall

22
Tank breathing from cooling of rain and wind:

Ts : a r × (Ts - Tr ) - a g × (Tg - Ts ) = - s × r s × cs ×
dTs
dt
V dTg
Tg : a g (Tg - Ts ) = - × r g × c g ×
A dt

The timely change of the temperatures is proportional to the sum of

convective heat in and output

23
Temperature distribution on the Tank Wall during cooling
from water film

24
 E.g. the heat transferred by the rain has to be considered:

~
a r × (Ts - Tr ) = re × r r × c r × (Tr - Tu ) + a u × (Tr - Tu ) + b u × r u × (y r - y u ) × hr
& ~

1 2 3 4

1: heat transfer from wall to rain film

2: heat up of the rain film through the wall
3: cooling of the rain film through the heat transfer to environment
4: cooling of the water film by evaporation to the wind

25
 Solution if solving differential equation:

300 Maximum volume flow 55

VG,B

240
45
Volume Flow V in m3/h

Temperature J in oC
180 JG

35

120

JW
25
60
Maximum volume flow occurs
at maximum delta T

0 15
0 180 360 540 720 900
Time t in s
26
Thermal - inbreathing simplified as in ISO 28300

&
Vthermal -in = Cin VT R in
0,7

vapour pressure
Cin haxane or similar higher than hexane,
or unkown
storage temperature
latitude < 25 °C ≥ 25°C < 25 °C ≥ 25°C
> 58° 2,5 4 4 4
42° - 58° 3 5 5 5
< 42° 4 6,5 6,5 6,5

Rin = reduction factor insulation

Vt = tank volume

27
Comparison – inbreathing

100000

10000
volume flow [m³/h]

1000

100

3180 m³
10
100 1000 10000 100000
tank volume [m³]

TRbF ISO / EN 42°-58° API H/D=0,5

API H/D=1,5 API H/D=2

28
 Calculation – Examples
Tank 1

Tank:
Height: 5m
Diameter: 7m
Tank volume: 192.4 m3
Pump in rate: 96 m3/h
Pump out rate: 96 m3/h
Vertical tank
No insulation
MAWP: + 7.5 mbar
MAWV: - 2.5 mbar

29
 Inbreathing Requirements (Total) for Tank 1

Inbreathing requirements Tank 1

400

350
Venting requirements [m3/h]

300

250

200

150

100

50

0
ISO ISO 28300
API 2000 EN28300
14015, ISO
EN28300
14015, 14015, 42- ISO
EN28300
ISO EN28300
14015, 42- ISO
EN28300
14015, EN 14015, TRbF 20
North, VP North, VP> 58, VP Hexane 58, VP> South, VP South, VP>
Hexane Hexane Hexane Hexane Hexane

Pump out Thermal

30
Resulting Vent Sizing for Tank 1 - Inbreathing
(pressure/vacuum vent, venting directly to atmosphere)

API 2000 5th : 3”

ISO 28300, VP Hexane (and storage T<25C), North: 3”

ISO 28300, VP >Hexane (and storage T=>25C), North: 4”
ISO 28300, VP Hexane, 42-58: 3”
ISO 28300, VP >Hexane, 42-58: 4”
ISO 28300, VP Hexane, South: 4”
ISO 28300, VP >Hexane, South: 4”
TrbF 20: 4”

31
 Outbreathing Requirements (Total) for Tank 1

Outbreathing requirements Tank 1

250
226
200
Venting requirements [m3/h]

150 H/D = 0.5

H/D = 0.71
123 130 H/D = 2

116 117
100 118 122
109

50

0
API 2000, FP API 2000, FP EN 14015, EN 14015, 42- EN 14015, TRbF 20 TRbF 20-2 TRbF 20-3
<37.8C >=37.8C North 58 South

Pump in Thermal

32
Resulting Vent Sizing for Tank 1 - Outbreathing
(pressure/vacuum vent, venting directly to atmosphere)

API 2000 (FP< 37.8C, BP>148.9C): 3”

API 2000 (FP=> 37.8C, BP=>148.9C): 2”

ISO 28300, North: 2”

ISO 28300, 42-58: 2”
ISO 28300, South: 2”
TrbF 20 (H/D=0.71): 2”
TrbF 20 (H/D=0.5): 2”
TrbF 20 (H/D=2): 2”

But, smallest vent size determined by vacuum side: at least 3”

33
 Calculation – Examples
Tank 2

Tank:
Height: 7m
Diameter: 10.45 m
Tank volume: 600 m3
Pump in rate: 200 m3/h
Pump out rate: 200 m3/h
Vertical tank
No insulation
MAWP: 7.5 mbar
MAWV: 2.5 mbar

34
 Inbreathing Requirements (Total) for Tank 2

Inbreathing requirements Tank 2

900

800
Venting requirements [m3/h]

700

600

500

400

300

200

100

0
API 2000 EN 14015, EN 14015, EN 14015, 42- EN 14015, 42- EN 14015, EN 14015, TRbF 20
North, VP North, VP> 58, VP Hexane 58, VP> South, VP South, VP>
Hexane Hexane Hexane Hexane Hexane

Pump out Thermal

35
Resulting Vent Sizing for Tank 2 - Inbreathing
(pressure/vacuum vent, venting directly to atmosphere)

API 2000 5th : 4”

EN 14015, VP Hexane, North: 6”

EN 14015, VP >Hexane, North: 6”
EN 14015, VP Hexane, 42-58: 6”
EN 14015, VP >Hexane, 42-58: 6”
EN 14015, VP Hexane, South: 6”
EN 14015, VP >Hexane, South: 6”
TrbF 20: 6”

36
 Outbreathing Requirements (Total) for Tank 2

Outbreathing requirements Tank 2

600

500
Venting requirements [m3/h]

400

H/D = 0.67 H/D = 1

H/D = 2
300

200

100

0
API 2000, FP API 2000, FP EN 14015, EN 14015, 42- EN 14015, TRbF 20 TRbF 20-2 TRbF 20-3
<37.8C >=37.8C North 58 South

Pump in Thermal

37
Resulting Vent Sizing for Tank 2 - Outbreathing
(pressure/vacuum vent, venting directly to atmosphere)

API 2000 (FP< 37.8C): 3”

API 2000 (FP=> 37.8C): 2”

EN 14015, North: 2”
EN 14015, 42-58: 3”
EN 14015, South: 3”
TrbF 20 (H/D=0.67): 2”
TrbF 20 (H/D=1): 2”
TrbF 20 (H/D=2): 2”

But, smallest vent size determined by vacuum side: at least 4”

38
 Calculation – Examples
Tank 3

Tank (real example out of petroleum industry):

Height: 12.75 m
Diameter: 35.66 m
Tank volume: 12,734 m3
Pump in rate: 795 m3/h
Pump out rate: 1272 m3/h
Vertical tank
No insulation
MAWP: + 7.5 mbar
MAWV: - 2.5 mbar

39
 Inbreathing Requirements (Total) for Tank 3
Inbreathing requirements Tank 3

7000

6000
Venting requirements [m3/h]

5000

4000

3000

2000

1000

0
API 2000 EN 14015, EN 14015, EN 14015, EN 14015, EN 14015, EN 14015, TRbF 20
North, VP North, VP> 42-58, VP 42-58, VP> South, VP South,
Hexane Hexane Hexane Hexane Hexane VP>
Hexane

Pump out Thermal

40
Resulting Vent Sizing for Tank 3 - Inbreathing
(pressure/vacuum vent, venting directly to atmosphere)

API 2000 5th : 1x 12”

EN 14015, VP Hexane, North: 2x 10”

EN 14015, VP >Hexane, North: 2x 10”
EN 14015, VP Hexane, 42-58: 2x 10”
EN 14015, VP >Hexane, 42-58: 2x 12”
EN 14015, VP Hexane, South: 2x 10”
EN 14015, VP >Hexane, South: 3x 10”
TrbF 20: 2x 12”

41
 Outbreathing Requirements (Total) for Tank 3

Outbreathing requirements Tank 3

3500

3000
Venting requirements [m3/h]

2500 H/D = 0.36

H/D = 0.5
2000

1500

1000

500

0
API 2000, FP API 2000, FP EN 14015, North EN 14015, 42-58 EN 14015, South TRbF 20 TRbF 20-2
<37.8C >=37.8C

Pump in Thermal

42
Resulting Vent Sizing for Tank 3 - Outbreathing
(pressure/vacuum vent, venting directly to atmosphere)

API 2000 (FP< 37.8C): 8”

API 2000 (FP=> 37.8C): 6”

EN 14015, North: 6”
EN 14015, 42-58: 6”
EN 14015, South: 8”
TrbF 20 (H/D=0.36): 6”
TrbF 20 (H/D=0.5): 6”

But, smallest vent size determined by vacuum side: at least 1x 12”

43
 Calculation – Examples
Tank 4

Large Size Tank:

Height: 15 m
Diameter: 45 m
Tank volume: 23,856 m3
Pump in rate: 1,000 m3/h
Pump out rate: 1,000 m3/h
Vertical tank
No insulation
MAWP: 7.5 mbar
MAWV: 2.5 mbar

44
 Inbreathing Requirements (Total) for Tank 4

Inbreathing requirements Tank 4

9000

8000
Venting requirements [m3/h]

7000

6000

5000

4000

3000

2000

1000

0
API 2000 EN 14015, EN 14015, EN 14015, 42- EN 14015, 42- EN 14015, EN 14015, TRbF 20
North, VP North, VP> 58, VP Hexane 58, VP> South, VP South, VP>
Hexane Hexane Hexane Hexane Hexane

Pump out Thermal

45
 Resulting Vent Sizing for Tank 4 - Inbreathing
(pressure/vacuum vent, venting directly to atmosphere)

API 2000 5th : 2x 10”

EN 14015, VP Hexane, North: 2x 10”

EN 14015, VP >Hexane, North: 3x 10”
EN 14015, VP Hexane, 42-58: 2x 10”
EN 14015, VP >Hexane, 42-58: 3x 12”
EN 14015, VP Hexane, South: 3x 10”
EN 14015, VP >Hexane, South: 4x 10”
TrbF 20: 3x 12”

46
 Outbreathing Requirements (Total) for Tank 4

Outbreathing requirements Tank 4

4500

4000
Venting requirements [m3/h]

3500

3000

2500

2000

1500

1000

500

0
API 2000, FP API 2000, FP EN 14015, North EN 14015, 42-58 EN 14015, South TRbF 20
<37.8C >=37.8C

Pump in Thermal

47
Resulting Vent Sizing for Tank 4 - Outbreathing
(pressure/vacuum vent, venting directly to atmosphere)

API 2000 (FP< 37.8C): 10”

API 2000 (FP=> 37.8C): 8”

EN 14015, North: 8”
EN 14015, 42-58: 8”
EN 14015, South: 10”
TrbF 20 (H/D=0.36): 10”

But, smallest vent size determined by vacuum side: at least 2x 10”

48
 Calculation – Examples
Tank 5

Very Large Size Tank (outside of scope of API 2000 5th ):

Height: 15 m
Diameter: 75 m
Tank volume: 66,268 m3
Pump in rate: 1,400 m3/h
Pump out rate: 1,400 m3/h
Vertical tank
No insulation
MAWP: + 7.5 mbar
MAWV: - 2.5 mbar

49
 Inbreathing Requirements (Total) for Tank 5

Inbreathing requirements Tank 5

18000

16000
Venting requirements [m3/h]

14000

12000

10000

8000

6000

4000

2000

0
API 2000 EN 14015, EN 14015, EN 14015, 42- EN 14015, 42- EN 14015, EN 14015, TRbF 20
North, VP North, VP> 58, VP 58, VP> South, VP South, VP>
Hexane Hexane Hexane Hexane Hexane Hexane

Pump out Thermal

50
Resulting Vent Sizing for Tank 5 - Inbreathing
(pressure/vacuum vent, venting directly to atmosphere)

API 2000: 3x 10”

EN 14015, VP Hexane, North: 3x 12”

EN 14015, VP >Hexane, North: 5x 10”
EN 14015, VP Hexane, 42-58: 4x 10”
EN 14015, VP >Hexane, 42-58: 6x 10”
EN 14015, VP Hexane, South: 5x 10”
EN 14015, VP >Hexane, South: 7x 12”
TrbF 20: 6x 12”

51
 Outbreathing Requirements (Total) for Tank 5

Outbreathing requirements Tank 5

10000

9000

8000
Venting requirements [m3/h]

7000

6000

5000

4000

3000

2000

1000

0
API 2000, FP API 2000, FP EN 14015, North EN 14015, 42-58 EN 14015, South TRbF 20
<37.8C >=37.8C

Pump in Thermal

52
Calculation example considering insulation:

• Tank volume 592,000 barrel

• Stored liquid Bitumen
• Pump in 4542 barrel/h
• Pump out 5458 barrel/h
• Insulation Calciumsilicate
• Insulation thickness 2”

53
 Overview Venting Requirements
(API 2000, ISO 28300)

API 2000 (without consideration of insulation):

• Inbreathing: 111 Nm3/min » 3,920 scfm
• Outbreathing: 70 Nm3/min » 2,472 scfm

ISO 28300 (without consideration of insulation):

• Inbreathing: 267 Nm3/min » 9,429 scfm
• Outbreathing: 132 Nm3/min » 4,662 scfm

54
How to consider insulation during thermal in- and out-
breathing

Reduction factor for insulation according to ISO 28300

1
R IN =
h × LIN
1+
l IN
l = heat conduction coefficient

h = heat transfer coefficient

LIN = thickness of insulation

Here: RIN = 0.2145

55
 Overview Venting Requirements
(API 2000 5th , ISO 28300)

API 2000 5th (without consideration of insulation):

• Inbreathing: 111 Nm3/min » 3,920 scfm
• Outbreathing: 70 Nm3/min » 2,472 scfm

ISO 28300 (with insulation):

• Inbreathing: 69 Nm3/min » 2,437 scfm
vs. 9,429 scfm
• Outbreathing: 38 Nm3/min » 1,342 scfm
vs. 4,662 scfm

56
 Emergency Venting for Hexane
Assumptions made (no insulation)

API 2000 5th

Molecular Weight 86.17 kg/kmol
latent heat of vaporization 334.9 kJ/kg/144 BTU

EN 14015
Molecular Weight 86 kg/kmol
latent heat of vaporization 335 kJ/kg/144BTU

57
ISO 28300 – Emergency Venting (SI Units)

Q×F æ T ö
0 .5

q = 906.6 × ×ç ÷
L èM ø
Q = Heat input from fire exposure depending on
wetted surface area and design pressure of
tank
F = Environmental factor
L = Latent heat of vaporization
T = Absolute temperature
M = Molecular mass of vapor

58
Example 1: very small tank

• height: 2m
• diameter: 1.5m
• vertical tank, no insulation

Results of emergency venting calculation:

EN 14015: 1,499 Nm3/h

API 2000: 3,030 Nm3/h

Þ API 2000 5th more conservative than EN 14015

59
Example 2: small tank

• height: 5m
• diameter: 7m
• vertical tank, no insulation

Results of emergency venting calculation:

EN 14015: 11,235 Nm3/h

API 2000: 15,738 Nm3/h

Þ API 2000 5th more conservative than EN 14015

60
Example 3: medium size tank

• height: 10m
• diameter: 10m
• vertical tank, no insulation, design
pressure < 1 psig

Results of emergency venting calculation:

EN 14015: 24,373 Nm3/h

API 2000: 21,032 Nm3/h

Þ EN 14015 more conservative than API 2000 5th

61
Example 4: large size tank

• height: 15m
• diameter: 30m
• vertical tank, no insulation, design
pressure < 1 psig

Results of emergency venting calculation:

EN 14015: 60,001 Nm3/h

API 2000: 21,032 Nm3/h

Þ EN 14015 more conservative than API 2000 5th

62
 Overview emergency venting for Hexane

70,000

60,000

50,000

API 2000: Required venting requirements

40,000 independent from wetted surface area/size of
m3/h

tank for wetted surface area > 2800 sqft

30,000

20,000

10,000

0
very small tank small tank medium tank large tank

EN 14015 API 2000, design pressure < 1psig

63
 Overview emergency venting for Hexane

Emergency Venting Requirements

70000

60000

50000

40000
m3/h

30000

20000

10000

0
0

0
11

15

19

25

60

80
35

45
2

11

15

20

26

80
30

50
Wetted surface area in m2

API 2000, design presure <= 1psig EN 14015 API 2000, design pressure > 1 psig

64
65
66
End of Presentation

Questions?

67