FIITJEE SOLUTION OF NSEC 2022-23

INDIAN ASSOCIATION OF PHYSICS TEACHERS

NATIONAL STANDARD EXAMINAITON IN CHEMISTRY
(NSEC-2022-23)
Time: 120 minutes Max. Marks: 216
Attempt All Sixty Questions
A–1
ONLY ONE OUT OF FOUR OPTIONS IS CORRECT BUBBLE THE CORRECTION OPTION

1. (D)
Sol. Reading in option (D) are close to 20 mL and less precise (relatively more gap between them).

2. (C)
Sol. Number of lines in spectrum depends on number of transition.
O O
Os

3. (B)
Sol. P  2 = 5RT
P  2 = 6RT
5RT = 6RT
5
T = T
6

4. (D)
Sol. 3A ⎯⎯
→ A3
( 0.9 )

K eq =
 A3 
A
3

0.9
=3
A
3

0.9
A
3
= = 0.3
3
[A] = 0.67 mol/dm3
5. (C)
Sol. G0 = 33.235 – 41.458 = −8.314
−8.314  103 = −2.303  8.314  288  log Keq

6. (A)
Sol. CH3 COOH + NaOH ⎯⎯
→ CH3 COONa + H2O
0.5x 4 0 0
0.5x − 4 0 4
4
4.74 = 4.57 + log
0.5 x − 4
4
0.17 = log
0.5x − 4
x = 13.5
7. (A)
Sol. → H+ + HSO−4
H2SO4 ⎯⎯
HSO−4 ⎯⎯
→ H+ + SO24−
H2O  H3 O+  HSO4−  SO24−  OH−
8. (D)
Sol. HA + BOH ⎯⎯ → AB + H2O
−3 −2
30  10 70  10 0 0
−2 −2
3  10 70  10 0 0
NCl (OH ) = 67  10
− −2

POH = −log 67  10−2 = 2 − log 67

= 0.1739

9. (D)
Sol. ( , , P,  ) are intensive.

10. (B)
Sol. O3 is not standard state of oxygen.
Diamond is also not the standard state of carbon.

11. (B)
Sol. 2CH6N2 ( ) + 5O 2 ( g) ⎯⎯→ 2N2 ( g) + 2CO2 ( g) + 6H2O ( g); rH10 = −2606 kJ
6H2O ( g) ⎯⎯ → 6H2O ( g) ; rH02 = 6  ( −44 ) kJ
2CH6N2 ( ) + 5O 2 ( g) ⎯⎯→ 2N2 ( g) + 2CO2 ( g ) + 6H2O ( )
−2606 − 264
 combH = = −1435 kJ / mole
2

12. (C)
Sol. Total moles of ions:
100 3.42
nNaCl = = 1.71
58.5
100 1.66
nMgSO4 = = 0.833
120
100 1.33
nCa(NO3 ) = = 0.4425
2
226
100 2.2
nK2CO3 = = 0.735
136
Tb = Kbm
m = total molality
Tb  Tb

13. (C)
Sol. pH  [H+] (Given)
 VO2+ 
for (B ) Q = 2
but it is not half cell reaction as electron are neither consumed nor
 VO3−  H+ 
released.
 V 3 + 
(C) Q = 2
 VO2+  H+ 
 2
H+   VO2+ 
(D) Q =    2 + 
 VO 
From Nearest equation:
0.0591
E = E0 − logQ
(n = 1)
For half – cell given in (C) H+   Q  Eelectrode 

14. (D)
Sol. Two electrons are involved / consumed for reaction of two molecules of PbSO 4.
Eit 303  10  1.5  60  60
W= = 170 gm
96500 96500

15. (A)
0.002 cm−1
Sol. H2O = 0.2 m−1 = = 2  10−5 s / cm
100
NaCl ( aq) = 5  10 −5 s / cm
NaCl = 3  10−5 s / cm
1000 NaCl
Hence, m = 10 sm2 / mol = 105 s cm2 / mole =
M
M = 3  10−7
1 mole
= 3  10 −7
V litre
V (in litre) = 3.33  106

16. (A)
Sol. As half life does not depend on concentration of ‘P’, hence for ‘P’ order is 1. While half life
doubles on doubling the concentration, hence order of ‘Q’ is zero.
Hence, r = k P Q = k P
1 0

17. (C)
1
Sol. Ca2+ ions per unit cell = 8  =1
8
1
O2− ions per unit cell = 6  = 3
2
Ti4+ ions per unit cell = 1
Hence CaTiO3 is correct answer.

18. (D)
Sol. B2H6 ⎯⎯⎯
NH3
→ B2H6 .2NH3 ⎯⎯

153 K → B3N3H6

(K ) (L )

NaBH4

BCl3 ⎯⎯⎯
NH4 Cl
473 K
→ B3N3H3 Cl3

( M) ( N)

19. (A)
−
Sol. →  Au ( CN)2  ( aq)+ OH−
Gold ore + CN− + H2O + O2 ⎯⎯
( X)
 − 2−
 Au ( CN)2  ( aq)+ Zn ⎯⎯
→ Au + Zn ( CN)4  (aq)
( Y)

20. (D)

21. (C)
Sol. → PbCl2  + AlCl3 ( aq )
Pb2 + + Al3 + + HCl ⎯⎯
AlCl3 ( aq) + OH− ⎯⎯
→ Al ( OH)3 
Al(OH)3 ppt red in alizarin.
22. (C)
Sol. 3Br2 + 6OH− ⎯⎯ → 5Br − + BrO3− + 3H2O
5 electrons are exchanged between 3 molecules of Br2.
Hence n – factor of Br2 = 5/3
M 3M
Equivalent weight of Br2 = =
5/3 5

23. (B)

24. (A)
Sol. According to spectro chemical series:
NO2−  NH3  H2O is the order of crystal field splitting energy. Hence the wavelength of the light
energy absorbed will be inversely related.

25. (A)
Sol. NO3− + H2SO4 ⎯⎯
→ HSO4− + HNO3
→Fe2 ( SO4 )3 + H2O + NO
HNO3 + FeSO4 + H2SO4 ⎯⎯
FeSO4 ( aq) + NO ⎯⎯⎯
H2 O
→ Fe (H2O )5 (NO ) SO4

26. (C)
Sol. 2H2S + SO2 ⎯⎯
→ 2H2O + 3S 

27. (C)
Sol. As2S3 (sol) is negatively charged sol, which will be coagulated by cations. Coagulation value
decreases if charge of coagulating ion increases.

28. (D)
Sol. Catenation tendency in group 14 decreases down the group.

29. (D)

30. D
OR OR
Sol. (p)
R H

(q) Silicones O Si O Si O
 (c) Ferrocene Fe

O
H
(s) Glyoxal H
O
O
(t)
Ethyl acetate H3C C O C2 H5
Cl
Cl Cl
(u) Gammaxene
Cl Cl
Cl
In p, q, r and u, E = O bond is not present.

31. (C)

Sol. H3C S H sp3 hybridized

32. (A)
Sol. Ni ( CO)4  → Tetrahedral geometry

NiCl4 2− → Tetrahedral geometry

2−
Ni ( CN)4  → Square planar geometry
 Option (A) is correct statement.

33. (C)
Observed specific rotation ( sample )
Sol. Optical purity =
Specific rotation of pure enantiomer
+6.76
=  100 = 50%
+13.52
ee = 50% means 50% sample is racemic mixture and 50% is pure enantiomer.
 Option (C) is correct.

34. (A)
Sol. It is a case of neighbouring group participation (NGP), so, configuration about chiral centre will be
retained.

35. (C)
3
2 1
Sol. 5 Correct name of the compound is
6 4
5-methyl-5-hexen-2-one
O
36. (C)
O

H
Sol. 7 sp2 hybridised carbon

37. (B)

Sol. (i), (iii) and (v) are not possible products.

38. (A)
Sol.
O OH OH
CH3 − Mg − I CH3 CH3
dry ether +
CH3
CH3
 X CH3
Diastreomeric pair

39. (D)
Sol. O O
1. LDA / THF
CH3 − 78o C

O
||
2. Ph − C − H
3. H2 O
TEA / R.T.

O O OH

CH2 Ph
O

H
2.

3. H2 O

O OH

Ph

40. (D)
Sol. Br

Cl

HNO3 / H2 SO 4
 (8)
NO2 NH2
NO2
Cl2 / FeCl3 H2 / Pt
 ( 2) ( 4)
Cl Cl

( 3 ) NaNO2 + H3 O+
0o C
+
Br N2

Cu2 Br2
HBr
Cl (9) Cl

41. (D)
Sol. H
Cat. hydrogenation

Chiral
achiral
( C6H12 ) ( C6 H14 )
3 − methyl − 1 − pentene

42. (B)
Sol. HO
O
H3C O
OH

O
multistriatin

43. (B)
Sol. COOH COO Na

+ NaOH ⎯⎯→ + H2 O

C7 H6 O2
(Molecular mass = 122 g mol-1)

15
C7 H6 O2 + O2 ⎯⎯→ 7CO2 + 3H2 O
2
44. (B)
Sol. H H H H
O O O
> > >
O O O O O O O
Acidity order of highlighted hydrogen atoms.

45. (D)
Sol. O
NH2 O O HN C CH3

H3C C O C CH3

Cl (I) Cl (II)
(6%) (94%)
Compound (II) will be soluble in aq. Na2CO3 but (I) will not.

46. (C)
46. OH OH
Cl Cl
⎯⎯⎯⎯
→ Cl2
Excess

tBu tBu
Cl
OH
Br
Br2
Excess

tBu
Br
OH
I

I2
Excess
tBu

47. (C)
47. O O
H3C CH2 C OH ⎯⎯⎯⎯⎯
Excess NH3

→ H3C CH2 C NH2
C 3H 6O 2 (A) C3H7 ON (B )

P2O5 / 

NH2 ⎯⎯⎯⎯ ⎯ H3C

Metal hydride
H3C CH2 CH2 reduction CH2 C N
C3H9N (D ) C3H5N ( C )
Oxidation

Complete hydrolysis

NaNO2 / HCl O
H3C CH2 C OH
(A)
H3C CH2 CH2 OH
(E )
48. (D)
48. CH3 COOH COOH COOH COOH

⎯⎯⎯⎯ → ⎯⎯⎯⎯⎯ → ⎯⎯⎯⎯

KI
→
0
⎯⎯⎯⎯⎯ →
KMnO4 3H2 , Pt or Ni HNO2 , 0 C
 Solution

NO2 NO2 NH2 N2 I

ANY NUMBER OF OPTIONS 4, 3, 2 or 1 MAY BE CORRECT

MARKS WILL BE AWARDED ONLY IF ALL THE CORRECT OPTIONS ARE BUBBLED

49. (B, D)
49. Integrated rate equation for zero order reaction:
Ro − R = kt ... (i)
For first order reaction:
Rate = k R  ... (ii )
[R]o-[R]

 R 
ln  o  = kt ... ( iii )
 R  Time

50. (A, C)
50. (A → B) process is isochoric process in which P will increase with increase in temperature.
(B → C) process is isothermal expansion.
(C → A) process is isobaric process in which volume will decrease with decrease in temperature.

51. (A, C)
51. For SrF2: KI (0.005) (0.0005)2 = 125  10−11
KI > Ksp
For BaF2: KI = (1.0  10−4) (1.0  10−2)2 = 1  10−8
KI < Ksp
Ca (IO3 )3 ( s ) Ca3 + ( aq )+ 3IO3− ( aq )
( s) ( 3s )
Ksp = 27 s4
Ca (PO4 )3 ( s ) 3Ca3 + ( aq )+ 2PO34− ( aq )
( 3s ) ( 2s )
Ksp = (3s)3(2s)2 = 108 s5

52. (B, D)
52 Mass of gas per g of adsorbent will decrease with temperature of adsorption.
Different gas molecules have different rate of adsorption.

53. (A, B, C, D)
53. (Dehydration reaction)
KMnO4 + H2SO4 ⎯⎯ → Mn2O7 + KHSO4 + H2O
( Oily green)
O O

Mn Mn
O O O
O O \

54. (C)
54. Schottky defect decreases the density of the substance.
Dopping NaCl with SrCl2 will leave vacancies on half of the sodium ions left. Sr occupy half of the
space left by sodium ions.
55. (A, B, C)
55. At pH = 10, EBT will exist as:
O
O
S O will not ionise at pH = 10
OH
O
N
N
O
N
O (dianion species)
So, EBT can act as monodentate or bidentate ligand.

56. (A, B)
56.  All PI3, AsI3 and SbI3 are covalent compounds.
 PI3 > AsI3 > SbI3 (decreasing tendency of hydrolysis)
 Compound Boiling Point
PI3 ……………………………200C
AsI3 …………………………..403C
SbI3 …………………………..401C

57. (A, B, C)
57. O O H

O
H2 O K eq  1

O
O O H
H
Cl Cl O
K eq  1
H2 O
Cl C CH O Cl C CH

Cl Cl O
H
OH
O
H2 O
K eq  1
2
sp OH
( less angle strain than parent ketone )

58. (A, B, C)
58.  Since anomeric carbon is a chiral carbon, so given sugar can exist in two anomeric
pyranose forms.
 Since it is in hemiacetal, so it can reduce to tollen’s reagent to silver mirror.
 HO O OH OMe O OMe

HO OH OMe OMe
OH OMe
(Reducing sugar) (Non-reducing because anomeric
-OH is not - free
  HO O OH HO
CH2 OH
⎯⎯⎯⎯
→
NaBH4

HO OH HO OH
OH OH

59. (B, D)
59.  NH2 N2 Cl

NaNO2 + HCl
⎯⎯⎯⎯⎯
268 K
→

Et Et
(Stable)
H3C NH2 H3C N N H3C OH

NaNO2 + HCl
⎯⎯⎯⎯⎯
268 K
→ ⎯⎯⎯
H2 O
→

Et Et
(Unstable)

60. (B, D)
60.  O OH

COOH COOH
⎯⎯⎯⎯
NaBH4
or
→
DIBAL −H

O OH

COOH CH2 OH
⎯⎯⎯→ LiAlH4
or
B2H6