DAYANAND COLLEGE

HISAR
Affiliated to Guru Jambheshwar University of Science & Technology, Hisar
Under DAV College Managing Committee, New Delhi
(Accredited with Grade ‘A’ by NAAC)

DEPARTMENT OF CHEMISTRY
Laboratory Manual

Page | 1
 Contents

Sr. Titles Page No.

No.
1
General Facts about Labs 3
 Infrastructure and Maintenance
 Purchasing Procedure
 General Utilization Procedure
2
Postgraduate Practicals 4-7
 Course code: ACP-501 Inorganic Chemistry
 Course code: ACP-502 Organic Chemistry
 Course code: ACP-503 Physical Chemistry
3
Undergraduate Practicals (Paper Codes) 8-19
 Course code: CCP- 109 Practical –I
 Course code: CCP 209 Practical –II
 Course code: CCP-309 PRACTICAL-III
 Course code: CCP-409 PRACTICAL-IV
 Course code: CCP-509(i) PRACTICAL-V(i)
 Course code: CCP-509(ii) PRACTICAL-V(ii)
 Course code: CCP-609(i) PRACTICAL-VI(i)
 Course code: CCP-609(ii) PRACTICAL-VI(ii)
4
List of Instruments/ Equipments 20-21
5
Photographs of Laboratory/Instruments/ Equipments 22-27

Page | 2
 General Facts about Labs

 Infrastructure and Maintenance

Department of Chemistry has four laboratories named as Chem. Lab-1, Chem. Lab-2, Chem.

Lab-3 & Chem. Lab-4 which are maintained by Mr. Lalit, Mr. Jagminder, Mr. Sanjay Vasisth

and Mr. Satish Kumar respectively for its cleanness and distribution of equipments to the

students. We have our own scanner cum printer and Wi-Fi system. The Department has its

separate store for Chemical and equipment maintained by Mr. Sanjay Kumar (store keeper) in

a proper way.

Purchasing Procedure

Any demand requirement or discrepancy raised by the Lab attendants is brought into the

notice of Principal. Application is written after which the order form is filled. Quotation

invited is signed by the departmental purchase committee and then the lowest priced items

quoted are purchased as per GST rules. All procedure is executed through college “Central

Purchase and Maintenance Committee of the college.

 General Utilization Procedure

Students are divided into groups for smooth running of practical classes in labs. The related

equipments and chemicals are issued to the students as per their schedule. Separate registers

for equipment are maintained by Lab attendants on daily basisand issued to different Labs

when needed. Models are prepared in our Lab by the students for participating in District and

State Level Science Exhibitions.

Page | 3
 POSTGRADUATE PRACTICALS
[Link]. Chemistry 1st & 2nd Semester
Inorganic Chemistry
Practical -I

Course code: ACP-501

240 Hrs (8Hrs /week) Marks for Major Test (External): 140
Credits: 8 Marks for Internal Exam: 60
Exam Time: 8 Hrs (two sessions of 4hrs each) Total Marks: 200

I Water Analysis
1. Determination of dissolved oxygen in a water sample.
2. Determination of chemical oxygen demand of a waste water sample.
3. Determination of the amount of bleaching powder required to disinfect a water
sample byHorrock’s test.
4. Determination of total chlorine residuals.
5. Determination of free and combined chlorine residuals.
6. To determine the minimum dose of a coagulant required to coagulate a given sample
by Jar test and to compare the effectiveness of aluminium sulphate and ferric sulphate
as coagulants for a given sample at room temperature.
7. Determination of total suspended solids dried at 103-1050C
8. Determination of total dissolved solids dried at 1800C
9. Determination of fixed and volatile solids.
10. Determination of chloride content of a water sample by Mohr’s Method.

II Qualitative Analysis
Ten unknown mixtures will be given containing four radicals out of which one must be
an insoluble and one may be an acid radical and two metal ions.
(a) Less common metal ions – Tl, Mo, W, Ti, Zr, Th, V, U (two metal ions in cationic/anionic
forms)

(b) Insoluble– oxides (Al2 O3, Cr2O3, SnO2, TiO2, SiO2), sulphates (PbSO4, BaSO4), halides
(AgCl, AgBr, AgI).

(c) Acid radicals CO342-, HCO3 -, SO3 2-, SO4 2-, CH3 COO-, S2-, PO4 3-, NO3 -, NO2 -, Cl, Br-, I-,
C2O 2- etc.
III Preparations
Preparation of the following compounds and their spectroscopic studies.
1. VO (acac)2
2. NH4[Cr (NH3) 2 (CNS) 4]
3. Mn(acac)3
4. Na3[Co (NO2)6]
5. Hg [Co (NCS) 4]
6. Potassium trioxalatoferate (III) Trihydrate.
7. Dichlorobis (hydroxylamine) Zinc (II).
8. Pentathioureadicuprous nitrate.
9. Potassium trioxalato cobaltate (III).
10. Carbonato tetra-ammine cobalt (III) nitrate.
Page | 4
 [Link]. Chemistry 1st & 2nd Semester
Organic Chemistry
Practical -I
Course code: ACP-502

240 Hrs (8Hrs /week) Marks for Major Test (External): 140
Credits: 8 Marks for Internal Exam: 60
Exam Time: 8 Hrs (two sessions of 4hrs Each) Total Marks: 200

I Separation and Purification Techniques

Recrystallisation, Distillation: simple, fractional, steam and vacuum distillation, extraction,
chromatography: thin-layer and column chromatography and Gas Chromatography.

II Qualitative Analysis
Separation and identification of organic binary solid mixtures having acidic, basic and neutral
components using water, NaHCO3, NaOH, HCl and ether. Preparation of suitable derivatives of
isolated compounds.

III Organic Synthesis

Preparation of organic compounds Acetylation: Acetylation of cholesterol. Oxidation: Adipic
acid from cyclohexanol.
Aldol condensation: Dibenzal acetone from benzaldehyde. Sandmeyer reaction: p-
Chlorotoluene from p-toluidine.

Other preparations involving different types of organic reactions may be included.

Books Suggested:

1. Vogel’s Textbook of Practical Organic Chemistry, A.R. Tatchell, John Wiley.

2. Organic Chemistry -A Lab Mannual, D.L. Pavia, G.M..Lampman, G.S. Kriz,
R.G. Engel, Cengage Learning
3. Practical Organic Chemistry, F.G. Mann, B.C. Saunders, Orient Longman
4. Experiments and Techniques in Organic Chemistry, D. Pasto, C. Johnson and
M. Miller, Prentice Hall.
5. Macroscale and Microscale Organic Experiments, K.L. Williamson, D.C. Heath.
6. Systematic Qualitative Organic Analysis, H. Middleton, Adward Arnold.
7. Handbook of Organic Analysis-Qualitative and Quantitative, H. Clark, Adward
Arnold.

5
 [Link]. Chemistry
1st & 2nd Semester
Physical Chemistry
Practical -I

Course code: ACP-503

240 Hrs (8Hrs /week) Marks for Major Test (External): 140
Credits: 8 Marks for Internal Exam: 60
Exam Time: 8 Hrs (two sessions of 4hrs each) Total Marks: 200
I Refractometry
1. Determine the refractive index of simple organic liquids like methyl acetate, ethyl
acetate, methanol, ethanol, n-hexane, chloroform.
2. Determine the refractivity and molar refractivity of some organic liquids like methyl
acetate, ethyl acetate, methanol, ethanol, n -hexane, chloroform.
3. Determine the molar refractilities for CH2, C, H and Cl.
4. Study the variation of refractive index with concentration for KCl solution and
thereafter determine the unknown concentration of given KCl solution.

II Polarimetry
1. a) Study the variation of angle of optical rotation with the concentration of any
optically active substance (sucrose or glucose) and thereafter determine the unknown
concentration of the same substance in given solution.
b) Determine the specific and molecular rotation of sucrose or glucose at number of
concentrations.
2. Study the kinetics of inversion of cane -sugar (sucrose) in presence of an acid.

III Potentiometry
1. Determine the standard electrode potential of Cu and Zn.
2. Determine the strength of a given solution of ferrous ammonium sulphate by
potentiometric titration with K2Cr2O7 solution.
3. Study the precipitation titration between KCl and AgNO3 potentiometrically.
4. Determine the strength of iodide, bromide and chloride in a mixture by potentiometric
titration with silver nitrate.

IV Conductometry
1. Determine the strength of strong acid by conductometric titration with strongbase.
2. Determine the strength of weak acid by conductometric titration with strong base.
3. Determine the strength of strong acid and weak acid in a mixture by conductometric
titrationwith strong base.
4. Study precipitation titration between KCl and AgNO3 conductometrically. Determine
thestrength of given solution of AgNO3.
5. Determine the basicity of mono-, di- and tri-basic acids conductometrically.

6
 6. Determine solubility and solubility product of sparingly soluble salts like PbSO 4,
BaSO4.

V pH-metry
1. Determine the strength of strong acid by pH-metric titration with strong base.
2. Determine the strength of weak acid by pH-metric titration with strong base.
3. Determine the dissociation constant of acetic acid using pH-meter.

VI Chemical Kinetics
1. Study the hydrolysis of methyl acetate in presence of hydrochloric acid.
2. Study saponification of ethyl acetate by sodium hydroxide solution using same initial
concentration of both the reactants.
3. Study saponification of ethyl acetate by sodium hydroxide solution taking the initial
concentration of ester and base to be different.

VII Viscosity
1. Determine the viscosity of methyl acetate and ethyl acetate using Ostwald viscometer.
2. Study the variation of viscosity with concentration for a glycerol solution using
Ostwald viscometer and thereafter determine the concentration of unknown solution of
glycerol.
3. Determination of molar mass of a polymer.

VIII Distribution Law

1. Determine distribution coefficient of ammonia between chloroform and water.
2. Determine the formula of the complex formed between copper (II) ion and ammonia
usingdistribution method.

IX Adsorption
1. Verify the Freundlich and Langmuir adsorption isotherms for adsorption of acetic
acid/oxalic acid on activated charcoal.

Books Suggested
1. Practical Physical Chemistry, A.M. James and F.E. Prichard, Longman.
2. Findley’s Practical Physical Chemistry, B.P. Lavitt, Longman.
3. Practical Physical Chemistry, S.R. Pa lit and S.K. De, Science.
4. Experimental Physical Chemistry, R.C. Da s and B. Behera, Tata McGraw Hill.
5. Experiments in Physical Chemistry, D.P. Shoemaker
6. Experiments in Physical Chemistry, D.V. Jahagirdhar.
7. Senior Practical Physical Chemistry by B.D. Khosla, V. Garg and A. Gulati.
8. Advanced Practical Physical Chemistry, J.B. Yadav, Goel Publishing House.

7
 SEMESTER-I
CCP- 109 Practical Chemistry
Section A: Inorganic Chemistry - Volumetric Analysis
1. Estimation of sodium carbonate and sodium hydrogen carbonate present in a mixture.
2. Estimation of oxalic acid by titrating it with KMnO4.
3. Estimation of water of crystallization in Mohr’s salt by titrating with KMnO4.
4. Estimation of Fe (II) ions by titrating it with K2Cr2O7 using internal indicator.
5. Estimation of Cu (II) ions iodometrically using Na2S2O3.
Section B: Organic Chemistry
1. Detection of extra elements (N, S, Cl, Br, I) in organic compounds (containing upto
two extra elements)
2. Separation of mixtures by Chromatography: Measure the Rf value in each case
(combination of two compounds to be given)
(a) Identify and separate the components of a given mixture of two amino acids (glycine,
aspartic acid, glutamic acid, tyrosine or any other amino acid) by paper chromatography
(b) Identify and separate the sugars present in the given mixture by paper chromatography.

Reference Books:
• Svehla, G. Vogel’s Qualitative Inorganic Analysis, Pearson Education, 2012.
• Mendham, J. Vogel’s Quantitative Chemical Analysis, Pearson, 2009.
• Vogel, A.I., Tatchell, A.R., Furnis, B.S., Hannaford, A.J. & Smith, P.W.G., Textbook of
Practical Organic Chemistry, Prentice-Hall, 5th edition, 1996.
• Mann, F.G. & Saunders, B.C. Practical Organic Chemistry Orient-Longman, 1960.

8
 SEMESTER-II

CCP 209 Practical -II

Chemistry Lab-II
CHEMICAL ENERGETICS, EQUILIBRIA & FUNCTIONAL ORGANIC
CHEMISTRY

Section A: Physical Chemistry

Thermochemistry
1. Determination of heat capacity of calorimeter for different volumes.
2. Determination of enthalpy of neutralization of hydrochloric acid with sodium hydroxide.
3. Determination of enthalpy of ionization of acetic acid.
4. Determination of integral enthalpy of solution of salts (KNO3, NH4Cl).
5. Determination of enthalpy of hydration of copper sulphate.
6. Study of the solubility of benzoic acid in water and determination of H. Ionic equilibria pH
measurements
a) Measurement of pH of different solutions like aerated drinks, fruit juices, shampoos and
soaps (use dilute solutions of soaps and shampoos to prevent damage to the glass electrode)
using pH-meter.
b) Preparation of buffer solutions:
(i) Sodium acetate-acetic acid
(ii) Ammonium chloride-ammonium hydroxide
Measurement of the pH of buffer solutions and comparison of the values with theoretical
values.
Section B: Organic Chemistry
1. Purification of organic compounds by crystallization (from water and alcohol) and
distillation.
2. Criteria of Purity: Determination of melting and boiling points.
3. Preparations: Mechanism of various reactions involved to be discussed. Recrystallisation,
determination of melting point and calculation of quantitative yields to be done.
(a) Bromination of Phenol/Aniline

9
(b) Benzoylation of amines/phenols
(c) Oxime and 2,4-dinitrophenylhydrazone of aldehyde/ketone
Reference Books
• Vogel, A.I., Tatchell, A.R., Furnis, B.S., Hannaford, A.J. & Smith, P.W.G.,
Textbook of Practical Organic Chemistry, Prentice-Hall, 5th edition, 1996.
• Mann, F.G. & Saunders, B.C. Practical Organic Chemistry Orient-Longman, 1960.
• Khosla, B. D.; Garg, V. C. & Gulati, A. Senior Practical Physical Chemistry, R. Chand &
Co.: New Delhi (2011).

10
 SEMESTER-III
CCP-309
PRACTICAL-III
CHEMISTRY LAB-III:(SOLUTIONS, PHASE EQUILIBRIUM, CONDUCTANCE,
ELECTROCHEMISTRY & FUNCTIONAL GROUP ORGANIC CHEMISTRY)
Section A: Physical Chemistry
Solutions: Determination of molecular weight of non volatile solute by Rast Method.
Phase equilibria: [Link] of the phase diagram of a binary system (simple eutectic)
using cooling curves.
ii. Determination of the critical solution temperature and composition of the phenol water

systemand study of the effect of impurities on it.

iii. Study of the variation of mutual solubility temperature with concentration for the
phenol water system and determination of the critical solubility temperature.
Conductance: [Link] of cell constant
ii. Determination of equivalent conductance, degree of dissociation and dissociation constant

of a weak acid.
iii. Perform the following conductometric titrations:

a. Strong acid vs. strong base

b. Weak acid vs. strong base
Potentiometry: Perform the following potentiometric titrations:
i. Strong acid vs. strong base
ii. Weak acid vs. strong base
iii. Potassium dichromate vs. Mohr's salt

Section B: Organic Chemistry

I. Systematic Qualitative Organic Analysis of Organic Compounds possessing
monofunctional groups (-COOH, phenolic, aldehydic, ketonic, amide, nitro, amines) and
preparation of one derivative.
II. [Link] of amino acids by paper/thin layer chromatography.
2. Determination of the concentration of glycine solution by formylation method.

11
3. Titration curve of glycine
4. Action of salivary amylase on starch
5. Effect of temperature on the action of salivary amylase on starch.
6. Differentiation between a reducing and a nonreducing sugar.

Reference Books:
 Vogel, A.I., Tatchell, A.R., Furnis, B.S., Hannaford, A.J. & Smith, P.W.G., Textbook of
Practical Organic Chemistry, Prentice-Hall, 5th edition, 1996.
 Mann, F.G. & Saunders, B.C. Practical Organic Chemistry Orient-Longman, 1960.
 Khosla, B. D.; Garg, V. C. &Gulati, A. Senior Practical Physical Chemistry, R. Chand &
Co.:New Delhi (2011).
 Ahluwalia, V.K. &Aggarwal, R. Comprehensive Practical Organic Chemistry, Universities
Press.

12
 SEMESTER-IV
CCP-409
PRACTICAL-IV
CHEMISTRY LAB IV: (TRANSITION METAL & COORDINATION CHEMISTRY,
STATES OF MATTER & CHEMICAL KINETICS)
Section A: Inorganic Chemistry
Semi-micro qualitative analysis (using H2S or other methods) of mixtures - not more than
four ionic species (two anions and two cations, excluding insoluble and interfering salts) out
4

of the following: Cations : NH +, Pb2+, Bi3+, Cu2+, Cd2+, Fe3+, Al3+, Co2+, Ni2+, Mn2+, Zn2+,
Ba2+, Sr2+, Ca2+, K+
Anions
3 : CO
2–
3 , S2–2 , SO
3 ,2S O 32–, NO –, CH COO3–, Cl–4, Br–, 4I–, NO
2–
3
–
, 2SO4 2-, PO 3-, BO 3-,
C O 2-,
(Spot tests should be carried out wherever feasible)
1. Estimate the amount of nickel present in a given solution as
bis(dimethylglyoximato)nickel
(II) in a given solution gravimetrically.
2. Estimation of (i) Mg2+ or (ii) Zn2+ by complexometric titrations using EDTA.
3. Estimation of total hardness of a given sample of water by complexometric titration.

Section B: Physical Chemistry

I. Surface tension measurement (use of organic solvents excluded).
a. Determination of the surface tension of a liquid or a dilute solution using a stalagmometer.
b. Study of the variation of surface tension of a detergent solution with concentration.
II. Viscosity measurement (use of organic solvents excluded).
a. Determination of the viscosity of a liquid or dilute solution using an Ostwald’s viscometer.
b. Study of the variation of viscosity of an aqueous solution with concentration of solute.
[Link] Kinetics
Study the kinetics of the following reactions by integrated rate method:
a. Acid hydrolysis of methyl acetate with hydrochloric acid.
b. Saponification of ethyl acetate.
c. Compare the strengths of HCl and H2SO4 by studying kinetics of hydrolysis of methyl

13
 acetate

Reference Books:
• Svehla, G. Vogel’s Qualitative Inorganic Analysis, Pearson Education, 2012.
• Mendham, J. Vogel’s Quantitative Chemical Analysis, Pearson, 2009.
• Khosla, B. D.; Garg, V. C. &Gulati, A. Senior Practical Physical Chemistry, R. Chand &
Co.: New Delhi (2011).

14
 SEMESTER-V
CCP-509(i)
PRACTICAL-V(i)
CHEMISTRY DSC LAB V(i) POLYMER CHEMISTRY
I. Polymer synthesis
1. Free radical solution polymerization of styrene (St) / Methyl Methacrylate (MMA) / Methyl
Acrylate (MA) / Acrylic acid (AA).
a. Purification of monomer
b. Polymerization using benzoyl peroxide (BPO) / 2,2’-azo-bisisobutylonitrile (AIBN)
2. Preparation of nylon 66
3. Interfacial polymerization, preparation of polyester from isophthaloyl chloride (IPC) and
phenolphthalein
a. Preparation of IPC
b. Purification of IPC
c. Interfacial polymerization
4. Redox polymerization of acrylamide
5. Precipitation polymerization of acrylonitrile
6. Preparation of urea-formaldehyde resin
7. Preparation of novalac resin/resold resin
8. Microscale emulsion polymerization of poly(methylacrylate).
II. Polymer characterization
1. Determination of molecular weight by viscometry:
a. Polyacrylamide-aq. NaNO2 solution
b. (Poly vinyl proplylidine (PVP) in water
2. Determination of the viscosity-average molecular weight of poly(vinyl lcohol) (PVOH) and
the fraction of “head-to-head” monomer linkages in the polymer.
3. Determination of molecular weight by end group analysis: Polyethylene glycol (PEG) (OH
group).
III. Polymer analysis
1. Estimation of the amount of HCHO in the given solution by sodium sulphite method
2. Instrumental Techniques

15
3. Preparation of polyacrylamide and its electrophoresis
*at least 7 experiments to be carried out.

Reference Books:
• M.P. Stevens, Polymer Chemistry: An Introduction, 3rd Ed., Oxford University Press, 1999.
• H.R. Allcock, F.W. Lampe & J.E. Mark, Contemporary Polymer Chemistry, 3rd ed. Prentice-
Hall (2003)
• F.W. Billmeyer, Textbook of Polymer Science, [Link]-Interscience (1984)
• J.R. Fried, Polymer Science and Technology, [Link]-Hall (2003)
• P. Munk& T.M. Aminabhavi, Introduction to Macromolecular Science, [Link] Wiley &
Sons (2002)
• L. H. Sperling, Introduction to Physical Polymer Science, [Link] Wiley & Sons (2005)
• M.P. Stevens, Polymer Chemistry: An [Link] University Press (2005).
• Seymour/ Carraher’s Polymer Chemistry, 9th [Link] Charles E. Carraher, Jr. (2013).

16
 SEMESTER-V
CCP-509(ii) PRACTICAL-V(ii)
CHEMISTRY DSC LAB V

Chemistry of Main Group Elements, Theories of Acids and Bases

1. Iodometric estimation of potassium dichromate and copper sulphate
2. Iodimetric estimation of antimony in tartaremetic
3. Estimation of amount of available chlorine in bleaching powder and household bleaches
4. Estimation of iodine in iodized salts.
5. Iodimetric estimation of ascorbic acid in fruit juices.
6. Estimation of dissolved oxygen in water samples.
7. Gravimetric estimation of sulphate as barium sulphate.
8. Gravimetric estimation of aluminium as oximato complex
9. Preparation of the following: potash alum, chrome alum, tetraamminecopper(II) sulphate
monohydrate, potassium trioxalatoferrate(III) (any two, including one double salt and one
complex).

Recommended Texts:
 Svehla, G. Vogel’s Qualitative Inorganic Analysis, Pearson Education, 2012.
 Mendham, J. Vogel’s Quantitative Chemical Analysis, Pearson, 2009.

17
 SEMESTER-VI
CCP-609(i) PRACTICAL-VI(i)
CHEMISTRY DSC LAB VI
Organometallics, Bioinorganic Chemistry, Polynuclear Hydrocarbons and UV, IR
Spectroscopy
Section A: Inorganic Chemistry
1. Separation of mixtures by chromatography: Measure the Rf value in each case.
(Combination of two ions to be given)
a. Paper chromatographic separation of Fe3+, A13+ and Cr3+ or
b. Paper chromatographic separation of Ni2+, Co2+, Mn2+ and Zn2+
2. Preparation of any two of the following complexes and measurement of their conductivity:
a. tetraamminecarbonatocobalt (III) nitrate
b. tetraamminecopper (II) sulphate
c. potassium trioxalatoferrate (III) trihydrate
Compare the conductance of the complexes with that of M/1000 solution of NaCl, MgCl2
and LiCl3.
Section B: Organic Chemistry
Systematic Qualitative Organic Analysis of Organic Compounds possessing monofunctional
groups (- COOH, phenolic, aldehydic, ketonic, amide, nitro, amines) and preparation of one
derivative.
Reference Books:
• A.I. Vogel: Qualitative Inorganic Analysis, Prentice Hall, 7th Edn.
• A.I. Vogel: Quantitative Chemical Analysis, Prentice Hall, 6th Edn.
• Vogel, A.I., Tatchell, A.R., Furnis, B.S., Hannaford, A.J. & Smith, P.W.G., Textbook of
Practical Organic Chemistry, Prentice-Hall, 5th edition, 1996.
• Mann, F.G. & Saunders, B.C. Practical Organic Chemistry Orient-Longman, 1960.

18
 SEMESTER-VI
CCP-609(ii)
Practical-VI(ii)
CHEMISTRY DSE LAB 6B: QUANTUM CHEMISTRY, SPECTROSCOPY &
PHOTOCHEMISTRY
UV/Visible spectroscopy
1. Study the 200-500 nm absorbance spectra of KMnO4 and K2Cr2O7 (in 0.1 M H2SO4) and
determine the λmax values. Calculate the energies of the two transitions in different units (J
molecule-1, kJ mol-1, cm-1, eV).
2. Study the pH-dependence of the UV-Vis spectrum (200-500 nm) of K2Cr2O7.
3. Record the 200-350 nm UV spectra of the given compounds (acetone, acetaldehyde, 2-
propanol, acetic acid) in water. Comment on the effect of structure on the UV spectra of organic
compounds. Colorimetry
1. Verify Lambert-Beer’s law and determine the concentration of CuSO4 / KMnO4 /K2Cr2O7
in a solution of unknown concentration
2. Determine the concentrations of KMnO4 and K2Cr2O7 in a mixture.
3. Study the kinetics of iodination of propanone in acidic medium.
4. Determine the amount of iron present in a sample using 1,10-phenathroline.
5. Determine the dissociation constant of an indicator (phenolphthalein).
6. Analyse the given vibration-rotation spectrum of HCl(g)
Reference Books
• Mendham, J. Vogel’s Quantitative Chemical Analysis, Pearson, 2009.
• Khosla, B. D.; Garg, V. C. &Gulati, A., Senior Practical Physical Chemistry, R. Chand & Co.:
New Delhi (2011).
• Garland, C. W.; Nibler, J. W. & Shoemaker, D. P. Experiments in Physical Chemistry8th Ed.;
McGraw- Hill: New York (2003).
• Halpern, A. M. &McBane, G. C. Experimental Physical Chemistry3rd Ed.; W.H. Freeman &
Co.: New York (2003).

19
 List of Instruments/ Equipments

Sr. No. Items Total

1 Atomic Model 7
2 Burner (LPG) 92
3 Balance 20
4 Burette Clamps 165
5 Conductivity Cell 3
6 Copper Plate 20
7 Clamps For Iron Stands 185
8 Counter Balance 2
9 Drying cone 84
10 Electric Oven 3
11 Air Blower 4
12 Distilled Water Plant (Steel) 3
13 Filter Pump 24
14 Foot Blower 1
15 Iron Stand 206
16 Muffle Furnace 1
17 Pastle Motor 10
18 Polythene Bottle 65
19 Ring Iron 50
20 Spatula 242
21 Send Bath 250
22 Stop Clock 4
23 Weight Box 98
24 Water bath 140
25 Zinc plate 20
26 Rotary Shaker 2
27 Digital Electronic Balance 12

20
28 Deionizer Water treatment plant 1
29 Separating Funnel (Polythene) 13
30 Tripod Stands 348
31 Refrigerator 2
32 pH Meter 8
33 Colorimeter 8
34 Avo Source 1
35 Magnetic Stirrer 2
36 Heating Mental 6
37 Conductivity Meter 15
38 Hot Plate 6
39 Stabilizer For Gas Plant 1
40 Melting Point app. 15
41 Water Bath Electric 1
42 Potentiometer 6
43 Telephone Set 1
44 Vacuum Pump 4
45 Centrifugal Machine 3
46 Abbe's Refractometer 6
47 TLC Applicator 1
48 Lab Scale 4
49 Computer and UPS 1
50 Spectrophotometer | 2
51 Cork Boring Machine 1
52 Interactive Bord With Projecter 1
53 PG Gas Cylinder 12
54 R.O. (Water Purifier 1
55 Laptop 1
56 Aluminium Box 24x 36" 2
57 Printer 2

21
Conductivity Meter Vaccum Pump

Distillation Assembly Hot Plate

22
Spectrophotometer Centrifugal Machine

Potentiometer Colorimeter

23
Melting Point Apparatus Abbe's Refractometer

Digital Balance Distillation Unit

24
Chemicals Saparating Funnel

Reagents Store Rooms

25
CHEMISTRY LABORATORIES

26
HEAD OFFICE &STAFF ROOMS

27