JEE (Main + Advanced) / Chemistry / SPP-01
SPP - 01
Single Correct Type Questions :
1. The frequency of a green light is 6 × 1014 Hz. Its wavelength is :-
(A) 500 nm
(B) 5 nm
(C) 5000 nm
(D) none of these
2. A proton accelerated from rest through a potential difference of 'V' volts has a some
wavelength 'λ' associated with it. An alpha particle in order to have the same wavelength
must be accelerated from rest through a potential difference of -
(A) V volt
(B) 4V volt
(C) 2V volt
(D) V volt
8
3. Which transition of electron in Li2+ would emit the photon whose wavelength will be same as
that of photon emitted by Hydrogen atoms corresponding to 2nd line of Balmer series.
(A) 6 → 12
(B) 8 → 4
(C) 8 → 2
(D) None of these
4. A compound containing 5 gm sulphur and 5 gm oxygen atom. Then empirical formula of the
compound is :
(A) SO
(B) SO2
(C) S2O
(D) SO3
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5. The minimum amount of O2(g) consumed per gram of reactant is :
(Given atomic mass : Fe = 56, O = 16, Mg = 24, P = 31, C = 12, H = 1)
(A) 4 Fe(s) + 3O2(g) → 2Fe2O3(s)
(B) P4(s) + 5O2(g) → P4O10(s)
(C) C3H8(g) + 5O2(g) → 3CO2(g) + 4H2O(I)
(D) 2Mg(s) + O2(g) → 2MgO(s)
6. Total number of electrons present in 4.4g oxalate ion (C2O24− ) is:-
(A) 0.05NA
(B) 2.3NA
(C) 2.2NA
(D) 2.1NA
Multiple Correct Type Questions :
7. If 27 g of Carbon is mixed with 88 g of Oxygen gas and is allowed to burn to produce CO2 ,
then
(A) Oxygen is the limiting reagent.
(B) Volume of CO2 gas produced at NTP is 50.4 L.
(C) C and O combine in mass ratio 3 : 8 in CO2
(D) Volume of unreacted O2 at NTP is 11.2 L.
8. 1st excitation potential for the H-like (hypothetical) sample is 24 V. Then which of the
following is/are correct ?
(A) Ionisation energy of the sample is 36 eV
(B) Ionisation energy of the sample is 32 eV
(C) Binding energy of 3rd excited state is 2 eV
(D) 2nd excitation potential of the sample is 32 8 V
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9. The density of air is 0.001293 g/cm3 at NTP. Identify which of the following statement is
correct
(A) Vapour density is 14.48
(B) Molecular weight is 28.96
(C) Vapour density is 0.001293 g/cm3
(D) Vapour density and molecular weight cannot be determined.
Integer Type Questions :
10. Average atomic mass of magnesium is 24.31 a.m.u. This magnesium is composed of
79 mole % of 24Mg and remaining 21 mole % of 25Mg and 26Mg. Calculate mole % of 26Mg.
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Answer Key
Question 1 2 3 4 5 6 7 8 9 10
Answer A D D B A B BCD BCD AB 10.00
SOLUTIONS SPP-01
1. Ans.(A)
c=×
3 × 108 m/sec = 6 ×1014 Hz ×
= 5 × 10–7 m = 500 nm
2. Ans.(D)
h
= (For proton) .....(A)
2meV
= (For particle) .....(B)
2( 4m )( 2e ) V '
M = 4Mp
q = 2e
Equating both (A) and (B) we have
2meV = 2 (4m) (2e) V'
V = 8V'
V
V' =
8
3. Ans.(D)
2nd line Balmer series (4 → 2) H – atom
1 1 1
= R.12 2 − 2 -------(A)
2 4
1 1 1
For Li2+ = R.Z2 −
( n /3)2 ( n /3)2
1 2
3 1 1
= R ( 3) 2 − 2
n1 n2
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2 1 1
= R.1 − -------(B)
n 2 n 2
2
1
3 3
Comparing (A) and (B) we get
n1 n
= 2; 2 = 4
3 3
n1 = 6 ; n2 = 12
The transition is 12 → 6
4. Ans.(B)
Element Mole ratio Simplest ratio
S 5 5 32
=1
32 32 5
O 5 5 32
=2
16 16 5
So, the formula is SO2
5. Ans.(A)
(a) 4Fe + 3O2 ⎯→ 2Fe2O3
1 g Fe requires = 3 32 = 0.43 g of oxygen
4 56
(b) P4 + 5O2 → P4O10
1 g of P requires = 5 32 = 1.3 g of oxygen
31 4
(c) C3H8 + 5O2 → 3CO2 + 4H2O
1 g of C3H8 requires = 5 32 = 3.6 g of O2
44
(d) 2Mg + O2 → 2MgO
32
1 g Mg requires = g = 0.66 g of O2
2 24
6. Ans.(B)
2−
Total electrons in one C2O4 = 46
Total number of e– = 46 × 4.4/88 NA = 2.3 NA
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7. Ans.(B,C,D)
C + O2 ⎯⎯
→ CO2
mass 27 88
27 88
moles
12 32
C is limiting reagent
Moles of CO2 produced = moles of C = 27 = 2.25
12
Volume of CO2 at NTP = 2.25 22.4 = 50.4 L
Ratio of C and O in CO2 = 12 : 32 = 3 : 8
Moles of unreacted O2 = 2.75 – 2.25 = 0.5
Volume of unreacted O2 at NTP = 0.5 22.4 = 11.2 L
8. Ans. (B,C,D)
1st excitation potential = 10.2 (Z2) = 24 V Z2 = 24/10.2
IE = 13.6 Z2 = 13.6 24 = 32 eV.
10.2
Binding energy of 3rd excited state = 0.85 Z2 = 0.85 24 = 2eV.
10.2
2nd excitation potential of sample = 12.09 Z2 = 12.09 24 = 32 8 V.
10.2 9
9. Ans.(A,B)
(A) and (B) [Link]. = d × volume of 1 mole of gas at NTP
M. Wt. = 0.001293 × 22400 = 28.96
V. D. = 28.96 = 14.48
2
So (A) and (B) are correct answer.
10. Ans. (10)
Let mole % of 26Mg be x.
(21 − x) 25 + x (26) + 79 (24)
= 24.31
100
x = 10%
Answer = 1.0
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