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Chemistry Model for Class 12: Periodic Table

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0% found this document useful (0 votes)
140 views38 pages

Chemistry Model for Class 12: Periodic Table

Uploaded by

guhankasi.j
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd

INDEX

[Link] TOPIC PAGES

1. INTRODUCTI 1-2
ON
2. HISTORY 3-5

3. STRUCTURE 6-7

4. S-BLOCK 8-9

5. P-BLOCK 10-12

6. D-BLOCK 13-17

7. F-BLOCK 18-20

8. DAILY 21-28
EXPERIMENT
S
9. CONCLUSIO 29
N
10. BIBLIOGRAP 31
HY
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INTRODUCTION

The Periodic Table is one of the most


fundamental and valuable tools in
chemistry, organizing all known elements
based on their atomic number, electron
configuration, and chemical properties. It
provides a systematic arrangement that
helps scientists understand the relationships
between different elements and predict their
behaviour in various chemical reactions.

The history of the periodic table dates back


to the early 19th century, when
scientists attempted to classify elements
based on similarities in their properties.
Dmitri Mendeleev's periodic table,
introduced in 1869, was a groundbreaking
achievement that laid the foundation for the
modern periodic table. Over time,
advancements in atomic theory and
discoveries of new elements led to
modifications in its structure, culminating in
the present-day periodic table based on the
1 modern periodic law proposed by Henry
Moseley.
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The periodic table is divided into groups,


periods, and blocks, each representing
elements with specific properties and
trends. These periodic trends, such as
atomic radius, ionization energy,
electronegativity, and electron affinity, play
a crucial role in understanding chemical
reactions and bonding. Furthermore, the
periodic table has extensive real-world
applications in various fields, including
medicine, industry, research, and
agriculture.

This project aims to explore the history,


structure, periodic properties, and
significance of the periodic table, providing
an in-depth understanding of its relevance
in scientific studies and daily life.

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HISTORY
Early Classifications of Elements
The classification of elements has evolved
through various attempts to organize
elements based on their properties. Early
scientists proposed different theories before
the development of the modern periodic
table.

1. Dobereiner’s Triads (1817)


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o Johann Wolfgang Döbereiner grouped


elements into triads based on similar
properties.
o The atomic mass of the middle
element was approximately the
average of the other two.
o Example: Lithium (Li), Sodium (Na),
and Potassium (K).
o Limitations: Only a few elements
could be arranged into triads.

2. Newlands’ Law of Octaves (1864)


o John Newlands arranged elements in
increasing atomic mass and
observed that properties repeated
every eighth element, similar to
musical octaves.
o Example: Lithium (Li), Sodium (Na),
and Potassium (K) exhibited similar
properties.
o Limitations: It did not work for
elements beyond calcium and was
not accepted universally.
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Mendeleev’s Periodic Table (1869)


One of the most significant contributions to
the classification of elements came from
Dmitri Mendeleev.
 Mendeleev arranged elements in
increasing order of atomic mass.
 He grouped elements with similar
chemical properties into columns.
 Left gaps for undiscovered elements and
predicted their properties accurately
(e.g., Gallium and Germanium).
 Strengths:
o Successfully classified most of the
known elements.
o Predictions about missing elements
were later confirmed.
 Limitations:
o Some elements did not fit the order
based on atomic mass (e.g., Argon
and Potassium).
o No explanation for the position of
isotopes.
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Modern Periodic Law (Henry Moseley,


1913)

 Henry Moseley discovered that atomic


number, not atomic mass, was the
correct basis for element arrangement.
 Modern Periodic Law states: The
properties of elements are periodic
functions of their atomic numbers.
 This resolved inconsistencies in
Mendeleev’s periodic table and led to
the current structure of the periodic
table.

Development of the Modern Periodic


Table

1. Introduction of Noble Gases


(1894-1900): The discovery of noble
gases (Helium, Neon, Argon, etc.) led to
the addition of a new group (Group 18).

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2. Glenn T. Seaborg’s Actinide


Series (1940s): Seaborg restructured
the periodic table by placing actinides
(like Uranium and Thorium) separately,
similar to lanthanides.

3. Discovery of New Elements:


Elements beyond uranium (transuranic
elements) were artificially synthesized,
extending the periodic table.
STRUCTURE

Groups and Periods

1. Groups (Vertical Columns)


o The periodic table consists of 18
vertical columns, called groups.
o Elements in a group have the same
number of valence electrons, which
determines their chemical reactivity.
o Groups are further divided into:

 Group 1: Alkali metals (e.g.,


Lithium, Sodium, Potassium)
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 Group 2: Alkaline earth metals


(e.g., Magnesium, Calcium)

 Groups 3-12: Transition metals


(e.g., Iron, Copper, Zinc)

 Group 17: Halogens (e.g.,


Fluorine, Chlorine)

 Group 18: Noble gases (e.g.,


Helium, Neon, Argon)
o Elements in the same group exhibit
similar chemical and physical
properties due to their identical
valence electron configurations.

2. Periods (Horizontal Rows)


o The periodic table has 7 horizontal
rows, called periods.
o Each period corresponds to the
number of electron shells an atom
has.
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o Elements within a period show a


gradual change in properties as the
atomic number increases.
o Moving from left to right across a
period:
 The atomic radius decreases.
 Ionization energy and
electronegativity increase.
 The metallic character decreases
while the non-metallic character
increases.
o The first period (Period 1)
contains only two elements
(Hydrogen and Helium), while the
rest contain increasing numbers of
elements.

S-BLOCK ELEMENTS

1. s-Block Elements:
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 Comprises Group 1 (Alkali Metals)


and Group 2 (Alkaline Earth Metals).
 Found on the left side of the periodic
table.
 Have one or two valence electrons,
making them highly reactive.
 Low ionization energy and large atomic
radii.
 Form basic oxides and hydroxides.
 Good conductors of heat and electricity.
 Exhibit metallic character, soft texture,
and low density.

Group 1: Alkali Metals

 Includes Lithium (Li), Sodium (Na),


Potassium (K), Rubidium (Rb), Cesium
(Cs), and Francium (Fr).
 Highly reactive, especially with water,
forming strong bases (alkalies).
 Reactivity increases down the group.
 Exist in nature only as compounds due
to high reactivity.
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 Low melting and boiling points compared


to other metals.
 Form ionic compounds and have a strong
tendency to lose their single valence
electron.

Group 2: Alkaline Earth Metals

 Includes Beryllium (Be), Magnesium


(Mg), Calcium (Ca), Strontium (Sr),
Barium (Ba), and Radium (Ra).
 Less reactive than alkali metals but still
react with water and acids.
 Reactivity increases down the group.
 Have higher melting and boiling points
compared to alkali metals.
 Form oxides and hydroxides that are less
soluble in water than those of alkali
metals.
 Play crucial roles in biological systems
(e.g., Calcium in bones and Magnesium
in enzymes).
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P-BLOCK ELEMENTS

 Found in Groups 13 to 18 of the


periodic table.
 Comprise metals, nonmetals, and
metalloids.
 Have 3 to 8 valence electrons in their
outermost shell.
 Show a wide range of chemical and
physical properties.
 Includes noble gases, halogens, and
metalloids.

Group 13: Boron Family


 Includes Boron (B), Aluminum (Al),
Gallium (Ga), Indium (In), and Thallium
(Tl).
 Boron is a metalloid; others are metals.
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 Form trivalent compounds (e.g., AlCl₃,


B₂O₃).

Group 14: Carbon Family


 Includes Carbon (C), Silicon (Si),
Germanium (Ge), Tin (Sn), and Lead (Pb).
 Carbon is a nonmetal; Silicon and
Germanium are metalloids, and Tin and
Lead are metals.
 Exhibit oxidation states of +4 and +2.

Group 15: Nitrogen Family


(Pnictogens)
 Includes Nitrogen (N), Phosphorus (P),
Arsenic (As), Antimony (Sb), and Bismuth
(Bi).
 Exhibit oxidation states of -3, +3, and
+5.
 Show a transition from nonmetallic (N, P)
to metallic (Sb, Bi) character.

Group 16: Oxygen Family


(Chalcogens)
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 Includes Oxygen (O), Sulfur (S),


Selenium (Se), Tellurium (Te), and
Polonium (Po).
 Oxygen is a vital element for life.
 Exhibit oxidation states of -2, +4, and
+6.

Group 17: Halogens


 Includes Fluorine (F), Chlorine (Cl),
Bromine (Br), Iodine (I), and Astatine
(At).
 Highly reactive nonmetals, forming salts
with metals.
 Exhibit oxidation states of -1, +1, +3,
+5, and +7.

Group 18: Noble Gases


 Includes Helium (He), Neon (Ne), Argon
(Ar), Krypton (Kr), Xenon (Xe), and Radon
(Rn).
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 Chemically inert due to a full valence


shell.
 Used in lighting, welding, and medical
applications.

D-BLOCK ELEMENTS
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3. d-Block Elements (Transition


Elements):
 Found in Groups 3 to 12 of the periodic
table.
 Also known as transition elements
because they exhibit properties that
transition between s- and p-block
elements.
 Have a partially filled d-orbital in at
least one of their oxidation states.
 Exhibit variable oxidation states and
form colored compounds.
 Show strong metallic character
(malleability, ductility, conductivity, and
high melting/boiling points).
 Often act as catalysts in industrial and
biochemical reactions.
 Form complex compounds due to the
availability of empty d-orbitals.

Groups of d-Block Elements

Group 3: Scandium Family


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 Includes Scandium (Sc), Yttrium (Y),


Lanthanum (La), and Actinium (Ac).
 Have a common oxidation state of +3.
 Scandium is used in aerospace
materials.
 Yttrium and its compounds are used in
superconductors and LEDs.

Group 4: Titanium Family


 Includes Titanium (Ti), Zirconium
(Zr), Hafnium (Hf), and
Rutherfordium (Rf).
 Common oxidation states: +2, +3, +4.
 Titanium is known for its strength and
corrosion resistance and is used in
aircraft and medical implants.
 Zirconium is used in nuclear reactors.

Group 5: Vanadium Family


 Includes Vanadium (V), Niobium (Nb),
Tantalum (Ta), and Dubnium (Db).
 Common oxidation states: +2, +3, +4,
+5.
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 Vanadium compounds are used in


catalysts and steel production.
 Tantalum is highly corrosion-resistant
and used in electronics.

Group 6: Chromium Family


 Includes Chromium (Cr), Molybdenum
(Mo), Tungsten (W), and
Seaborgium (Sg).
 Common oxidation states: +2, +3, +6.
 Chromium is used in stainless steel and
pigments.
 Tungsten has the highest melting point
of all metals and is used in filaments and
cutting tools.

Group 7: Manganese Family


 Includes Manganese (Mn),
Technetium (Tc), Rhenium (Re), and
Bohrium (Bh).
 Common oxidation states: +2, +4, +7.
 Manganese is essential in steelmaking
and biological enzymes.
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 Technetium is a radioactive element


used in medical imaging.

Group 8: Iron Family


 Includes Iron (Fe), Ruthenium (Ru),
Osmium (Os), and Hassium (Hs).
 Common oxidation states: +2, +3, +6.
 Iron is the most used metal in
construction and industry.
 Osmium is the densest naturally
occurring element.

Group 9: Cobalt Family


 Includes Cobalt (Co), Rhodium (Rh),
Iridium (Ir), and Meitnerium (Mt).
 Common oxidation states: +2, +3.
 Cobalt is used in magnets and
rechargeable batteries.
 Rhodium is highly reflective and is used
in automotive catalytic converters.

Group 10: Nickel Family


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 Includes Nickel (Ni), Palladium (Pd),


Platinum (Pt), and Darmstadtium
(Ds).
 Common oxidation states: +2, +3, +4.
 Nickel is used in coins and batteries.
 Platinum is used in jewelry and as a
catalyst in fuel cells.

Group 11: Copper Family (Coinage


Metals)
 Includes Copper (Cu), Silver (Ag),
Gold (Au), and Roentgenium (Rg).
 Common oxidation states: +1, +2, +3.
 Copper is an excellent conductor of
electricity and is used in electrical
wiring.
 Silver has the highest electrical and
thermal conductivity.
 Gold is highly resistant to corrosion and
is used in electronics and jewelry.

Group 12: Zinc Family


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 Includes Zinc (Zn), Cadmium (Cd),


Mercury (Hg), and Copernicium (Cn).
 Common oxidation states: +2.
 Zinc is essential for biological enzymes
and is used in galvanization.
 Mercury is the only liquid metal at room
temperature and is used in
thermometers and fluorescent lights.
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f-BLOCK ELEMENTS
. F-Block Elements (Inner Transition
Elements):
 The f-block elements are placed
separately at the bottom of the periodic
table and include lanthanides
(elements 57-71) and actinides
(elements 89-103).
 These elements have their valence
electrons in the 4f and 5f orbitals.
 They are known as inner transition
metals.

Lanthanides (Rare Earth Elements):


 Includes elements from Lanthanum
(La) to Lutetium (Lu).
 They have a common oxidation state of
+3.
 Exhibit high magnetic, optical, and
catalytic properties.
 Used in lasers, phosphors in LED
screens, and strong permanent
magnets.
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 Example: Neodymium (Nd) is used in


powerful magnets found in speakers and
wind turbines.

Actinides:
 Includes elements from Actinium (Ac)
to Lawrencium (Lr).
 Most actinides are radioactive.
 Common oxidation states include +3,
+4, +5, and +6.
 Uranium (U) and Plutonium (Pu) are
widely used in nuclear reactors and
atomic energy programs.
 Example: Thorium (Th) is a potential
fuel for future nuclear energy
generation.

Properties of f-Block Elements:


 High densities and melting points
(except some actinides like Uranium and
Thorium).
 Show variable oxidation states,
making them useful in catalysts.
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 Highly reactive, especially actinides,


which can oxidize rapidly in air.
 Lanthanide contraction: A gradual
decrease in atomic and ionic radii across
the lanthanide series due to poor
shielding by 4f electrons.
 Actinides are mostly radioactive,
making them hazardous but useful in
energy production.

Uses of f-Block Elements:


 Lanthanides are used in optical
devices, magnets, and electronics.
 Actinides like uranium and plutonium
are used in nuclear power plants.
 Thorium is used in gas mantles and
experimental nuclear reactors.
 Promethium (Pm) is used in luminous
paints and atomic batteries.
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DAILY EXPERIMENTS

S-Block
1. Reaction of Alkali Metals with
Water
 Materials Needed: A Small piece of
sodium/potassium, water, a beaker, and
phenolphthalein indicator.
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 Procedure: Drop a small piece of


sodium/potassium in water and observe
the vigorous reaction. Add
phenolphthalein to test the basicity.
 Observation: Formation of a strong
base (NaOH/KOH) and release of
hydrogen gas with flame.

 Reaction:

2. Reaction of Magnesium with


Acid
 Materials Needed: Magnesium ribbon,
dilute hydrochloric acid (HCl), test tube.
 Procedure: Add magnesium ribbon to
dilute HCl and observe the reaction.
 Observation: Formation of hydrogen
gas bubbles and heat release.

 Reaction:
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P-BLOCK
1. Test for Carbon Dioxide Using
Limewater
 Materials Needed: Limewater
(Ca(OH)₂), straw, beaker.
 Procedure: Blow air into limewater
through a straw.
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 Observation: Limewater turns milky


due to the formation of calcium
carbonate (CaCO₃), confirming the
presence of CO₂.

 Reaction:

2. Reaction of Sulfur Dioxide with


Water
 Materials Needed: Sulfur powder,
burner, water, pH paper.
 Procedure: Burn sulfur in air, dissolve
the gas in water, and test the pH.
 Observation: The Solution turns acidic
due to sulfurous acid formation.

 Reaction:

D-BLOCK
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1. Formation of Colored Complexes


 Materials Needed: Copper sulfate
(CuSO₄) solution, ammonia (NH₃).
 Procedure: Add ammonia dropwise to
the CuSO₄ solution.
 Observation: A deep blue complex
[Cu(NH₃)₄]²⁺ is formed, demonstrating
the ability of transition metals to form
colored compounds.

 Reaction:

2. Reaction of Iron with Copper


Sulfate
 Materials Needed: Iron nail, copper
sulfate (CuSO₄) solution, beaker.
 Procedure: Place an iron nail in CuSO₄
solution and observe after some time.
 Observation: The iron nail gets coated
with reddish-brown copper,
demonstrating a displacement reaction.

 Reaction:
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3. Oxidation of Chromium
 Materials Needed: Potassium
dichromate (K₂Cr₂O₇), sulfuric acid
(H₂SO₄), ethanol.
 Procedure: Mix K₂Cr₂O₇ with ethanol
and acidify.
 Observation: Orange color turns green
due to the reduction of Cr(VI) to Cr(III).

 Reaction:

4. Catalytic Action of Manganese


Dioxide
 Materials Needed: Hydrogen peroxide
(H₂O₂), MnO₂.
 Procedure: Add MnO₂ to H₂O₂ solution.
 Observation: Rapid release of oxygen
gas, MnO₂ acts as a catalyst.

25  Reaction:
(MnO₂ as catalyst)
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F-BLOCK
1. Glow of Radioactive Elements
 Materials Needed: Luminous watch
dial (containing promethium/radium-
based phosphors).
 Procedure: Observe the glow in the
dark.
 Observation: The glow is due to
radioactive decay exciting the phosphor
material, demonstrating the radioactive
nature of actinides.

2. Oxidation of Uranium
 Materials Needed: Uranium
compound, heat source, oxygen supply.
 Procedure: Expose uranium metal to
oxygen.
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 Observation: Formation of uranium


oxide (UO₂/UO₃), showing its reactivity.

 Reaction:

3. Neodymium Magnets
 Materials Needed: Neodymium
magnet, metal objects.
 Procedure: Use neodymium magnets to
attract metal objects.
 Observation: Extremely strong
magnetic force demonstrates the
practical use of lanthanides in magnets.

4. Europium in Fluorescent Lamps


 Materials Needed: Fluorescent tube
lamp (with europium compounds), power
supply.
 Procedure: Switch on the lamp and
observe the light.
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 Observation: The red glow in many


fluorescent lights is due to europium-
based phosphors, illustrating its role in
lighting.

5. Cerium in Gas Mantles


 Materials Needed: Gas lamp with
thorium-cerium oxide mantle.
 Procedure: Light the gas lamp and
observe the intensity of light.
 Observation: Cerium oxide glows
brightly when heated, used in older-style
gas mantles for lighting.

CONCLUSION

The Periodic Table stands as a cornerstone


of modern chemistry, representing a
culmination of centuries of scientific
inquiry and discovery. Through this
project, we explored the evolution of the
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periodic table from early attempts by


Dobereiner and Newlands to the more
refined contributions of Mendeleev and the
eventual development of the modern
periodic law by Moseley. Each milestone in
the table’s development reflects
humanity's persistent quest to understand
the fundamental structure of matter.

The modern periodic table is more than


just an arrangement of elements; it is a
powerful tool that allows scientists to
predict properties, understand element
behavior, and navigate the vast world of
chemical reactions. The categorization of
elements into s, p, d, and f blocks based
on their electronic configurations brings
clarity to their chemical characteristics
and their roles in daily life and industrial
applications.

Our investigation into the properties of


block elements—such as the highly
reactive alkali metals of the s-block, the
versatile and essential non-metals of the
p-block, the colored and catalytic d-block
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elements, and the radioactive and rare


earth f-block elements—has revealed the
diversity and importance of chemical
elements. Furthermore, we discovered
how these elements appear in everyday
experiences, from the reaction of baking
soda with vinegar to the glow of
phosphors in lamps, the role of transition
metals in colored compounds, and the use
of neodymium in powerful magnets.

These daily life experiments reinforce the


relevance of chemistry in our routine
activities and highlight the dynamic
interplay between
confined to laboratories; it is embedded in
the materials we use, the food we eat, the
technology we depend on, and the
environment we strive to protect.

In conclusion, the periodic table is not a


static chart, but a living document—
constantly updated as new elements are
discovered and our understanding of
atomic structure deepens. Its significance
in education, research, and industry
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cannot be overstated. This project has not


only deepened my appreciation of the
periodic table’s structure and utility but
also inspired a broader respect for the
science of chemistry and its role in
shaping the world around us. As we look to
the future, the periodic table will continue
to serve as a guide in the exploration of
new materials, sustainable solutions, and
scientific innovation.

BIBLIOGRAPHY
1. [Link]
1. c5dc-8001-81ed-f43cc7cd014c

2. NCERT Chemistry Textbook Class 12


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3. Modern’s ABC Chemistry Book

4. [Link]

[Link]
5.

[Link]
6.

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