Smart Sensors in Green Packaging Quality
Smart Sensors in Green Packaging Quality
Gazi Farhan Ishraque Toki , Anik Das , Rezaul Karim Khan Alave ,
and Rony Mia
Abstract There has been a lot of research into chemical and biosensor develop-
ment over the last several decades, and that has led to some fascinating new sensor
devices that could be useful in many fields, including food technology. A new kind of
environmentally friendly food packaging called “smart” or “intelligent” has emerged
by integrating these sensors. Integrating knowledge from several disciplines, these
systems draw on food technology, science, chemistry, biochemistry, electronics, and
physics. Smart packaging keeps tabs on food quality and safety throughout the supply
chain, from farmers to consumers, using chemical or bio-type sensors. Many other
kinds of sensors that measure things like time, temperature, carbon dioxide, oxygen,
pathogens, freshness, and leakage can be created using this technology. Online assur-
ance of quality and security for consumers, authorities, and food producers is a must,
and this technology shows enormous promise for expanding the capabilities of green
packaging with sensors that go beyond the existing state of the art in areas such as
controlling the food’s volume, color, and appearance.
G. F. I. Toki
Nanotechnology Center, School of Fashion and Textiles, The Hong Kong Polytechnic University,
Kowloon 999077, Hong Kong
A. Das
School of Textile Science and Engineering, Tiangong University, Tianjin 300387, People’s
Republic of China
R. K. K. Alave
Shanghai Frontier Science Research Center for Modern Textiles, College of Textiles, Donghua
University, Shanghai 201620, People’s Republic of China
R. Mia (B)
Wilson College of Textiles, North Carolina State University, 1020 Main Campus Dr,
Raleigh 27606, NC, United States
e-mail: mroni_mia@[Link]
Department of Textile Engineering, National Institute of Textile Engineering and Research,
University of Dhaka, Dhaka 1000, Bangladesh
© The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. 2025 359
S. ul Islam and M. Shahid (eds.), Green Materials for Active Food Packaging,
Engineering Materials, [Link]
360 G. F. I. Toki et al.
11.1 Introduction
Fig. 11.1 The eco-friendly influence of packaging throughout time. Republished with the permis-
sion of Elsevier [5]. Copyright Elsevier, 1998
discarded within a year, posing a noteworthy solid leftover topic, mostly when not
adequately managed. Consumers often associate plastics with adverse environmental
consequences, notably plastic pollution in marine environments. While Life Cycle
Assessments (LCA) can quantify the ecological influence of various packing ingre-
dients, disparities in methodology and system boundaries complicate comparisons.
International policies such as bans on single-use plastics and initiatives for mini-
mizing plastic waste are imperative. Bioplastics derived from renewable sources
offer promise, although constraints exist. Approximately half of bioplastics are
non-biodegradable and pose similar environmental risks as conventional plastics.
Biodegradable bioplastics often necessitate specific composting conditions, which
many consumers are unaware of leading to improper disposal [38].
Sustainable packaging is a crucial aspect of various industries, aiming to mini-
mize environmental impact while ensuring product protection. This concept encom-
passes three foremost scopes, for instance, the economy, the environment, and human
well-being. Ideally, sustainable packaging should contribute to a fairer distribution of
resources and maintain a healthy ecosystem [39, 40]. From an ecological perspective,
materials like glass are often considered more sustainable than plastic or aluminum
cans due to their reusability. However, plastic remains the most extensively utilized
packaging material as a result of its lightweight nature, lower rate, and moldability
[41]. A shift towards material recycling, reuse, and the development of bio-based
as well as ecological materials is necessary to achieve true sustainability. Packaging
is vital in product protection, storage, and delivery, but its production and disposal
significantly affect the environment. Studies have shown that packaging contributes
to greenhouse gas emissions, resource depletion, and pollution. Single-use plastics,
for instance, pose a particular threat due to their extensive use and long lifespan in
landfills [42]. Many countries and organizations are implementing regulations and
initiatives to promote sustainable packaging. The European Union (EU), for example,
has restricted the usage of only-usage plastics, while country like Pakistan is progres-
sively shifting towards executing the UN’s Sustainable Development Goals, focusing
on waste collection, recycling, and infrastructure development [43, 44]. Despite its
benefits like extended shelf life, multi-layered packaging presents challenges in recy-
cling due to the complexity of separating its various materials. Regulations are being
enforced to limit its use and encourage the adoption of more recyclable alternatives
like polyolefins [45, 46]. The concept of green packaging emphasizes the use of
eco-friendly materials that minimize waste and pollution. This approach is gaining
traction due to growing consumer awareness and regulations imposed by authori-
ties. However, implementing green packaging strategies often requires overcoming
obstacles related to cost, technological advancements, and human resource skillsets.
Sustainable Supply Chain Management (SSCM) integrates ecological considerations
throughout the supply chain, encompassing production, packaging, and logistics.
Green supply chain management (GSCM) takes this a step further, directing to lessen
the ecological impact of an entire organization’s operations [47]. Reusable pack-
aging, particularly plastic packaging, is being increasingly utilized for its efficiency
and cost-effectiveness in reverse logistics. Solid waste management (SWM) remains
364 G. F. I. Toki et al.
11.3.1 O2 Detectors
Fig. 11.2 a A colorimetric redox dye-based O2 sensor, b)Color changes for various CO2 levels from
0 to 23%, c a colorimetric CO2 sensor utilizing a food-grade combination composed of an amino
acid (l-lysine), a polypeptide (poly l-lysine, EPL), and naturally occurring colors (anthocyanins).
Republished with permission from ACS [52]. Copyright © 2019 American Chemical Society
upholding food quality [60, 61]. Various sensor types have been devised for moni-
toring O2 levels within MAPs, each harboring distinct advantages and constraints.
While luminescent sensors offer heightened sensitivity, their detection necessitates
specialized apparatus [51, 62–64]. Colorimetric redox sensors furnish a simpler alter-
native but mandate specific storage and handling protocols. Light-activated systems
and phosphorescent sensors entail additional limitations concerning dye migration
[65, 66]. Recent strides employing alginate polymers hold promise in addressing dye
migration concerns, thereby enhancing O2 monitoring within MAPs [53].
366 G. F. I. Toki et al.
Optical sensors designed for sensing CO2 levels in the context of food pack-
aging can be considered into two basic kinds. For instance, luminescent dye-based
sensors undergo a fluorescence change when they come into contact with CO2 , and
colorimetric indicators rely on pH indicators to generate significant color changes
[67–69].
To effectively utilize luminous dyes, sophisticated equipment is necessary for
both stimulating and detecting the light emitted by the dyes. This includes portable
instrumentation and handheld scanning devices. Although luminous dyes provide
excellent analytical performance, their deployment is not without difficulties [70–
72]. Researchers pioneered the development of this technology. The addition of
HPTS (8-Hydroxypyrene-1,3,6-trisulfonic acid) onto a plastic sheet was the method
they used to achieve it [73]. Consequently, a fluorometric CO2 sensor was developed
with a rapid response and restoration time. Scientists improved the HPTS system’s
stability by immobilizing the fluorophore molecule in a hydrophobic progressively
altered silica (ormosil) matrix and enhancing sensitivity using a dual luminophore
referencing system [71]. It is crucial to remember that the chemical constituents
utilized in sensor production are not suitable for food consumption. Consequently, it
is essential to take strict procedures to avoid the sensors from contacting food items
[70].
Recent research on CO2 sensors for food packaging has primarily focused on
using colorimetric indicators [68]. While bright dyes have higher sensitivity, these
indicators have relatively lower sensitivity. However, they have several advantages,
including using more affordable components and eliminating the requirement for
additional instrumentation instruments. Colorimetric pH dyestuff, for instance, m-
cresol purple, have produced thin, vibrant plastic films that exhibit color changes
when protonated or deprotonated [74]. Water-based systems provide excellent dura-
bility, especially for products that prerequisite to be kept at a humidity and temper-
ature level that can be accurately regulated [70]. Furthermore, empirical designs
utilizing food-grade blends have been validated, rendering them appropriate for mass
production of labels that offer customers clear indications about food preservation.
However, CO2 leak indicators often exhibit less reliability than O2 gas sensors.
This occurs when food undergoes CO2 absorption in the initial days of storage,
resulting in a reduced CO2 content in the headspace. This behavior is particularly rele-
vant to active pharmaceutical administration (MAP), where the package is initially
flushed. Conversely, the metabolic activity of microbes could lead to a rise in CO2
levels, potentially masking signs of leaks. Commercially accessible CO2 -sensitive
MAP indicators, including plastic optical fluorescent films, may demonstrate irreg-
ular reversibility due to oxygen consumption caused by microbial growth. This can
lead to compromised package integrity and the indication color remaining unaltered,
creating the perception that the package is still intact even if it has spoiled [55].
The fluctuations in CO2 levels during storage are the main factor contributing to
the perception that CO2 readings are often less reliable than O2 indicators. However,
11 Smart Sensors for Quality Monitoring in Green Packaging Solutions 367
CO2 indicators are still utilized to detect leaks. Furthermore, the metabolic activity
of bacteria might lead to misleading signals, adding complexity to the assessment of
detection precision. Several factors must be considered when using O2 and CO2 indi-
cators to identify leaks in MAP [52]. The challenges associated with O2 indicators
are their poor sensitivity, the complexity of handling, the lack of clear color change
in the presence of acidic CO2 , and the undesired reversibility [52, 75]. Although
many advanced platforms are now technologically advanced for detecting contami-
nants and pathogens, most of these platforms necessitate the extraction of samples
to identify specific molecules. Regarding food packaging applications, the main
emphasis is on identifying the development of microbiological contamination. This
necessitates incorporating integration within the package, clear-cut reactions that
are readily distinguishable, and cost-effective manufacturing. Tracking alterations in
the gas composition of a package due to microbial growth can provide as an indi-
rect means of identifying microbial contamination. Gas sensors can be employed to
achieve this objective [76]. The rise in CO2 concentration can function as a signal of
contamination or the presence of pathogens in packages that do not employ CO2 as a
protective gas. However, the detection of CO2 has challenges in accurately detecting
the proliferation of microbes in MAPs [76].
Humidity sensors are utilized to detect the moisture amount in food wrapping in real
time. Their purpose is to maintain optimal conditions and prolong the shelf life of
the food. Ensuring the humidity levels in food packing are at their best is crucial
for preventing rotting and preserving the eminence of the product. The demand for
extended shelf life in packaged goods has been directed to the creation of advanced
humidity sensors for the purpose of real-time observation (Fig. 11.3) [92–95]. Tan
et al. investigated using an economical substance for a wireless sensor intended for
on-site measurement of moisture levels in dry food packaging [95]. The sensor incor-
porates a flat coil and capacitor onto a paper base strategically positioned taking place
the inside surface of the packaging. As the level of humidity rises, which is frequently
an indication of a decline in food quality, the paper material absorbs water vapor. The
absorption modifies the capacitance of the capacitor and, consequently, the sensor’s
resonant frequency. The resonant frequency is determined via wireless measure-
ment techniques by examining the impedance detected in the linked coil. Feng et al.
11 Smart Sensors for Quality Monitoring in Green Packaging Solutions 369
Fig. 11.3 a An LC-type humidity sensor positioned on the inner wall of the packaging offers a
wireless response detected by a dedicated coil connected to the sensor reader unit, b Wireless
in-package humidity monitoring system. Reproduced from Ref. [92], Copyright CC-BY terms,
2007
TTIs are an essential technology in the food sector. They deliver a visual representa-
tion of a product’s temperature times gone by (Fig. 11.4). These devices operate by
converting temperature exposure into at least one detectable and lasting alteration,
accomplished through several methods such as physical changes, chemical reactions,
electrochemical responses, enzymatic processes, or even microbial activity [104,
105]. The “Fresh Check” indication (TempTime Corporation, USA) is a commer-
cially accessible TTI system with a solid-state polymerization process. This tech-
nique utilizes a thin layer of acetylenic monomer, which is transparent and lacks
color initially. However, with time, it undergoes a chemical change and transforms
into a polymer that is highly colored and opaque. The rate of this polymerization
reaction is directly affected by the temperature to which the sensor is subjected [106].
TTI sensors are classified according to their level of contact with the food product.
Temperature fluctuations can cause many alterations in food, such as mechanical,
chemical, electrochemical, enzymatic, or microbiological changes. Therefore, these
sensors provide essential information about patterns of food spoilage [107–109].
TTIs can be classified into three core divisions, such as critical time–temperature
indicators, complete history indicators, and critical temperature indicators [106].
Critical temperature indicators exclusively give evidence about the degradation of a
product and changes in its sensory characteristics resulting from temperature varia-
tions beyond a predetermined threshold within a specified time. These sensors usually
depend on irreversible color changes that are visually noticeable in the indication
(Fig. 11.4a). Figure 11.4a illustrates a temperature sensor system that relies on an
enzyme activity. Thermal exposure causes a sensitive patch to change color, and if
it turns orange, it indicates that the product has been compromised [110].
Critical time–temperature indicators provide comprehensive information about
the combined influence of time and temperature on the excellence or safety of a
11 Smart Sensors for Quality Monitoring in Green Packaging Solutions 371
Fig. 11.4 a Biosensor for critical temperature monitoring with spoilage detection. b Time-
integrating critical temperature indicator for threshold breach duration. Republished with permission
from the American Chemical Society [52]. Copyright American Chemical Society, 2019
Microbial proliferation has a double impact on food quality. Firstly, the abundance
of naturally existing bacteria affects the microbiological quality of the product and is
linked to its deterioration. Furthermore, the proliferation of harmful bacteria, which
are frequently introduced due to improper handling or contamination at diverse
points in the food manufacturing procedure, presents substantial health hazards
(such as pathogenic strains of E. coli) [115]. Today, Bacteria are one of the main
reasons for foodborne losses and diseases, emphasizing their importance as a focus
for monitoring food safety [116]. Conventional procedures for detecting bacteria
mostly depend on advanced laboratory technologies such nucleic acid amplification,
bacterial culture, colony counting, and immunological analysis. Although these tech-
nologies provide outstanding sensitivity, they are typically laborious and not easily
accessible for mass utilization [117–119]. Lately, scientists have concentrated on
372 G. F. I. Toki et al.
creating bacterial detection technologies that are user-friendly and simply under-
standable, with low need for user involvement. Nevertheless, most of these gadgets
are harmful and need the food item to be opened for analysis [120].
Lateral-flow immunoassays (LFIAs) are a method used to achieve user-
friendliness. These assays entail combining bacterial cells with antibody-conjugated
colloidal gold (Au) or palladium nanoparticles (PdNPs) and then putting the resulting
mixture on a test strip. The complexes are propelled along the strip by capillary
action and then collected by another immobilized antibody. This interaction leads to
the formation of a discernible colored line or spot, which serves as evidence of the
existence of bacteria (Fig. 11.5a). This technique provides a quick (about 15 min)
and equipment-free way for identifying bacteria, specifically Listeria monocytogenes
and Klebsiella bacterium [121–123]. Portable microfluidic devices provide an addi-
tional means for detecting germs. These devices, as demonstrated [124], consist of a
surface coated with gold that has been modified with antibodies capable of reacting to
certain antigens of E. coli. Bacterial aggregation can then be observed using bright-
field microscopy. The used the method of attaching E. coli-specific antibodies to Au
surfaces. It also included sensor chips to measure electrochemical signals in real-time
(Fig. 11.5b) [125].
Basu et al. have established a sensor for detecting E. coli that is made from flex-
ible acetate sheets containing graphene. This sensor employs electrodes for detec-
tion, utilizing graphene nanosheets that may capture E. coli bacteria and induce a
noticeable alteration in impedance spectroscopy [126]. DuVall et al. [127] created a
smartphone app that examines the clustering of paramagnetic silica beads to iden-
tify the existence of bacteria. This technique entails rupturing bacterial cells and
subsequently utilizing loop-mediated isothermal amplification (LAMP) to amplify
specific DNA strands.
Following the amplification of DNA, there is a following effect where the DNA
causes the beads to come together and form aggregates, as seen in Fig. 11.5c [128].
Yoon, Lee, and Park investigated the application of laser speckle decorrelation to
display the attendance of microbes in tissues. A static speckle pattern is observed
when a laser is reflected off uncontaminated food samples in a static turbid medium.
Nevertheless, the existence of living microbes generates a fluctuating speckle pattern
that may be measured to assess the extent of contamination (Fig. 11.5d) [129].
Although these methods show advancements in user-friendly bacterial identifica-
tion and their potential utility in monitoring food quality, they frequently necessitate
user involvement and the employment of intricate laboratory-based methodologies.
Methods for example microcontact printing, automated printers, and surface func-
tionalization, have been intensively studied to create patterns and add functionality
to surfaces to detect certain cells [130].
In a recent study, Yousefi et al. [130] introduced a significant breakthrough: a
straightforward device capable of detecting E. coli that can be simply merged into
food packing (Fig. 11.5e). This device shows great promise in identifying specific
bacteria in food models without the introduction of the box. This is a significant
achievement in advancing smart packaging sensors [130].
11 Smart Sensors for Quality Monitoring in Green Packaging Solutions 373
Fig. 11.5 a Lateral-flow test strip (LFT) schematic: A visible line in the testing zone specifies target
bacteria, b Microfluidic device with a gold sensor chip for real-time electrochemical detection of
E. coli using immobilized specific antibodies, c Paramagnetic silica bead aggregation intensifies
upon target bacteria DNA detection, d Laser speckle imaging detects microscopic movement. A
static, unmoving sample (like tissue) produces a static speckle pattern, while the presence of live
microorganisms causes a dynamic, fluctuating pattern, e A DNAzyme sensor embedded in a cyclo-
olefin polymer (COP) food wrap detects E. coli through a fluorescence signal increase. Republished
with permission from American Chemical Society [52]. Copyright American Chemical Society,
2019
on their capacity to provide convenience and prevent harmful interactions with the
food contents. In the 20th century, significant advancements in packaging tech-
nology occurred, which introduced systems that incorporated antibacterial agents
and oxygen-absorbing components. These advancements establish higher bench-
marks for extending food’s storage duration and protecting it from external factors,
sometimes called “active packaging” [131]. However, the food and beverage pack-
aging industry continues to experience ongoing challenges due to global trends such
as the increasing use of industrialized food processing, the rise in import and export
operations related to food products, and the growing desire for faster meal preparation
times. These factors encourage the investigation of advanced and complex packaging
options designed to satisfy the increasing customer demand for healthier, safer, func-
tional, and economically sustainable processed meals while still prioritizing conve-
nience. While the traditional perception of food packaging focused on protecting and
preserving the product, promoting convenience has quickly become just as impor-
tant. In modern food packaging design, factors such as traceability, tamper-proof
features, and sustainability have become crucial considerations [132–134].
This discussion explores the idea and foundations of “smart” or “intelligent”
packaging, with specific importance on incorporating sensor technology to enhance
the safety and quality of food [135, 136].
possible approach is to utilize printed signs that visually represent the freshness
levels of the products, or to incorporate QR codes that can be scanned to get
comprehensive information about the products.
5. Assistance with Opening and Ensuring Seal Integrity: Intelligent packaging can
aid in the process of opening the package and offer visual indicators to verify the
integrity of the seal, so ensuring the security and freshness of the goods.
6. Measures to prevent counterfeiting and theft: Intelligent packaging can be inte-
grated with functionalities to authenticate products, impede counterfeiting, and
discourage theft. This could entail the utilization of embedded radio frequency
identification (RFID) tags or tamper-evident seals [137].
Nevertheless, it is crucial to acknowledge that not all intelligent packaging solu-
tions will encompass every individual characteristic. In practical scenarios, the
primary emphasis is frequently placed on detecting and transmitting information
pertaining to the safety (indicating if food is safe or harmful) and quality (displaying
freshness, ripeness, or firmness) of a product [138, 139]. This focus on the status
of the product results in intelligent packaging that has the capability to: (a) Product
Tracking: The packaging has the capability to track the precise position of the product
at every stage of the supply chain, (b) Environmental Sensing: Sensors embedded
in the packaging can detect and measure both internal and external environmental
conditions, (c) Notify stakeholders: This data can be transmitted to manufacturers,
merchants, and customers, offering immediate and accurate knowledge on the safety
and quality of the product [140, 141].
The increasing need for extensive product information is fueling the expansion
of intelligent packing, namely in the food sector. Consumers are becoming more
inclined to comprehend component listings, storage suggestions, and instructions
for proper usage. Smart labels and stickers that employ thin-film technology can
fulfill this requirement by immediately conveying visual information to consumers
[89]. Smart packaging can incorporate disposal instructions and visual protection for
pharmaceutical and healthcare products, providing consumers with clear guidance
on how to use and dispose of them correctly. In addition, there is great potential for
developing drug delivery systems incorporated into intelligent packaging that may
transmit patient data to healthcare facilities. Wireless and electronic communication
for medicine delivery and patient data are still in the initial phases of expansion.
However, there is a possibility that they could be integrated into packaging in the
near future [142].
Another important aspect to consider is consumer confidence, especially
concerning perishable food items. The existing dependence on “best by” dates
frequently neglects to consider possible temperature variations during storage or
shipping, resulting in consumer uncertainty regarding the safety of a product [143].
In the future, there is potential for incorporating microbial growth indicators and TTIs
that rely on the chemical, physical, or enzymatic movement present in the food itself.
These developments will offer precise and unequivocal signals of product quality,
safety, and shelf-life. Scientists are currently engaged in the active development of
376 G. F. I. Toki et al.
novel TTIs, which provide a broader selection of choices for monitoring the dete-
rioration of food [142]. Smart packaging is a dynamic field that has the potential
to completely transform the way items are packaged, monitored, and delivered to
consumers. In this dynamic field, innovation will be driven by a continued emphasis
on features that improve product safety, quality, and consumer information.
Smart packaging refers to the usage of TTIs to monitor and control the tempera-
ture of products over time. TTIs are instruments that provide real-time info on the
temperature conditions that a product has been exposed to. This technology allows
for precise monitoring and ensures that products are transported and stored under
optimal temperature circumstances [142]. An innovation currently available in the
market is the integration of sensors into containers, enabling them to self-regulate
temperature by either heating or cooling. This technology transforms the containers
into “smart packaging” that informs consumers about the ideal temperature condi-
tions for the product. TTIs, which are commonly used sensors, can be exemplified
with thermochromic ink dots. These dots undergo a change in color when they reach
certain temperatures after being refrigerated or heated in a microwave. Illustrations
of this concept can be seen in pancake syrup containers that have dots to indicate the
optimal temperature for heating in a microwave, as well as in orange juice packaging
that visually shows when the refrigerated product is sufficiently cold to be consumed
[144]. The TTIs that are now accessible utilize various methods, which can be clas-
sified into three categories: chemical, physical, or biological. Chemical and physical
systems depend on reactions or alterations that are activated by time and temperature,
such as acid–base reactions, melting, or polymerization. Biological responses occur
when the biological activity of microbes, spores, or enzymes changes according to the
effects of time and temperature [142]. For example, 3 M’s MonitorMark™ provides
two options: an industrial threshold indicator and a consumer smart label. The indus-
trial variant serves as a gauge of misuse, lying dormant until a specific temperature
limit is surpassed. This technique utilizes a material that has a specified melting point
and is combined with a blue dye. A film strip is used to create a division between
the wick and a reservoir. When activated, the wick becomes visible. When exposed
to temperatures higher than its critical point, the substance will melt and spread into
the wick, causing it to turn blue. These indicators are offered in a range of critical
temperatures, spanning from −15 to 26 °C. The consumer version functions as a
semi-historical indicator, undergoing a color change when subjected to temperatures
that exceed the acceptable storage settings, and once more when the product reaches
the end of its shelf-life. The operational mechanism closely resembles that of the
industrial iteration, relying on the process of melting and diffusion of the blue dye
[145].
11 Smart Sensors for Quality Monitoring in Green Packaging Solutions 377
While TTIs like Fresh-Check and CheckPoint offer valuable tools for estimating
fish and meat freshness, researchers are exploring alternative methods for real-time,
non-invasive monitoring. One promising approach utilizes simple and inexpensive
chemical sensors that detect changes in fish pH. As fish spoils within a sealed package,
its pH level gradually increases due to the release of basic volatile amines. These
amines can be detected by a pH-sensitive sensor, offering a simple yet effective way to
track freshness. These sensors rely on the fundamental property of pH indicator dyes,
which change color based on the surrounding environment’s acidity or alkalinity. In
practice, these sensors can be constructed by entrapping a pH-sensitive dye (such as
bromocresol green) within a polymer matrix. This dye reacts visibly to the spoilage-
related volatile compounds, contributing to a measure known as TVB-N. This system
facilitates rapid and non-invasive detection of spoilage compounds in fish through a
colorimetric (color-based) method.
It’s important to note that while pH-based sensors offer a promising approach,
researchers are exploring various freshness indicator concepts. These concepts
explore the detection of different spoilage indicators like CO2 , amines, ammonia,
ethanol, and even hydrogen sulfide (H2 S). Integrating these indicators directly into
food packaging creates visible tags that change color in response to specific analytes,
providing a convenient and easy-to-understand method for consumers to assess food
freshness [146–149].
Active packaging methods encompass MAP and equilibrium MAP, which substitute
air with precisely regulated atmospheres. Typically, this involves reducing the amount
of O2 and increasing the level of CO2 . The ideal MAP for non-respiring foods entails
of 20–80% CO2 and 0–2% O2 [150–152]. Nevertheless, detecting MAP leaks poses
a challenging task. Gas leaks alter the composition by increasing the quantity of
378 G. F. I. Toki et al.
O2 and decreasing the quantity of CO2 . The modified environment encourages the
proliferation of aerobic bacteria, leading to food spoilage. In extreme situations,
the presence of microorganisms can effectively seal breaches by sustaining elevated
amounts of carbon dioxide. [153, 154].
Hence, the algorithms used for detecting MAP leaks must be sophisticated and
give priority to detecting O2 levels over CO2 levels. Commercial O2 -sensitive indica-
tors mostly concentrate on the functionality of O2 absorbers. Mitsubishi Gas Chem-
ical markets oxygen-absorbing sachets designed to decrease the presence of oxygen.
Furthermore, Cryovac-Sealed Air Ltd. has created an indicator that may be used
to confirm the gas composition of a package [142, 154, 155]. Visual O2 indicators
consist of redox dyes for example methylene blue, reducing agents such as sugars,
and alkaline substances such as sodium hydroxide. These items can take the form of
tablets, printed layers, or laminated film package inserts [142].
Despite its appropriateness, CO2 has downsides and absorbed by the product
once it is packaged and progressively accumulates in the space above the product
until it reaches a stable level. A significant decrease in CO2 emissions following
this initial period indicates the presence of a leak. The phenomenon known as the
Microbial Masking Effect: Leaks can result in the proliferation of microorganisms
and the generation of CO2 . The presence of CO2 may obscure the decrease in the
leak, resulting in a defective product that has normal levels of CO2 [156].
Although O2 indicators offer advantages, they also have disadvantages. Reduced
Sensitivity: highly sensitive O2 indicators may interact with small amounts of
remaining O2 (0.5–2.0%) that are occasionally present in properly sealed MAPs.
This might make the handling process more difficult and necessitate the use of
anaerobic preparation and packaging. Acidity Impact: MAPs containing CO2 gas
with an acidic nature may not exhibit a change in color of the oxygen indicator.
Reversible indicators are ineffective for detecting leaks. Microbial growth has the
ability to consume oxygen from a leak, which results in a change in the color of the
indicator and masks the process of deterioration.
Ultimately, the effectiveness of MAP leak detection is constrained by the O2 and
CO2 indicators. Scientists enhance the sensitivity, reliability, and clarity of response
to enhance the effectiveness of these food safety measures [157].
can be achieved using gas sensors as previously mentioned [159, 160]. Unfortunately,
the number of practical packaging indicators for contaminants or pathogens remains
scarce. While monitoring CO2 levels can signal microbial growth, it becomes a
challenge in MAP where CO2 is already present in high concentrations. Therefore,
CO2 monitoring as a sole indicator is only viable for non-CO2 -containing packages
[158].
For broader detection capabilities, conducting polymer biosensors offers another
promising avenue. These sensors function by sensing gases released throughout
microbial metabolism [161, 162]. They are designed by incorporating conducting
nanoparticles into an insulating matrix, with changes in resistance correlating to
the amount of gas released. These sensors have successfully detected foodborne
pathogens by analyzing bacterial cultures [163]. Additionally, coupling such sensors
with neural networks has confirmed potential in evaluating meat freshness. The
continuous development of these innovative biosensor technologies holds immense
promise for the future of food packaging, offering a more integrated and efficient
approach to food safety.
RFID tags have been used for many years to identify high-value products like elec-
tronics and clothing. These tags comprise two parts, like a microchip for processing
and storing information, and an antenna for transmitting and receiving data. A sepa-
rate reader device retrieves information from the tag, often at distances of numerous
meters liable on the radio frequency utilized. Notably, RFID tags in packaging are
passive, meaning they lack their own power source and rely on the reader’s radio
waves to transmit information [164]. The key benefit of RFID tags lies in their
ability to monitor multiple items throughout the entire supply chain. This signifi-
cantly enhances distribution speed and efficiency, especially crucial in today’s world
where raw materials travel from various regions to be processed in one location and
then distributed globally. RFID technology is envisioned to replace the widely used
barcodes of today.
Currently, silicon semiconductors are the primary material for RFID tags.
However, this may change to facilitate cheaper and easier production on various
materials. Developing printed electronics using conductive polymers and metallic
inks offers a promising alternative to traditional methods. Research institutions
and companies are actively exploring desktop inkjet printing and other high-
volume production techniques for printed electronics [161, 165]. Additionally, some
advancements are investigating the use of carbon nanotubes for RFID tag antennas
[166, 167], although this technology remains less developed than conductive inks.
Interestingly, researchers are exploring the integration of RFID tags with chemical
sensing functionalities. Prototypes for ethylene sensing (fruit ripeness) and mois-
ture detection demonstrate the potential of this technology [168, 169]. Nanotech-
nology offers a clear path for further advancements as these systems are inherently
microelectronic. Nanoscale barcodes, quantum dots, and magnetic nanoparticles are
380 G. F. I. Toki et al.
among the various systems being developed within the realm of nanotechnology.
Nanotechnology, which studies and manipulates materials at the molecular level,
has the latent to significantly reduce food spoilage and improve security throughout
production, processing, and shipping [132]. However, the widespread adoption of
such technologies in food packaging remains unclear due to cost and ease-of-use
considerations.
For RFID tags, the future holds promise beyond simple tracking. Integration
with functionalities like product authentication, anti-counterfeiting, and even theft
prevention could become commonplace.
More processing involving food is possible now that modern smart green pack-
aging innovation has laid a firm groundwork. Although this technology has a lot of
promising future uses, it might also face significant difficulties as it evolves. In this
part, we will go over a few of these obstacles and the possibilities for food-smart
green packaging.
The lack of advancements in sensory technology is a major roadblock to
smart packaging’s further growth. Incorporating sensors into large-scale packaged
containers is challenging due to their size, cost, and the fact that numerous sensors
could provide reliable readings for various freshness characteristics seen in food
goods. Technologists have always been interested in finding the sweet spot where
size, mobility, and functionality meet. The food business is particularly affected
by this issue because of the demand for affordable, widely available, high-quality
goods. The expansion of sensor-related nanotechnology research might provide a
solution to this problem. These sensors may pick up on a wide range of environ-
mental factors, including air pollutants, temperature, and humidity. Plus, they can do
more intrusive tests on food quality with little to no harm to the item. Although this
technique is now unfeasible for mass-produced food packaging, it has the potential to
be commercialized for extremely precise food quality sensing with additional study
[170]. Improving food quality sensors with the ability to use active packaging tech-
nology to deploy spoiling inhibitors is a major motivation. Antimicrobial packaging
is one area that could use some improvement in this area of research. To ensure the
safety of the product, food sanitization involves eliminating any microorganisms.
Currently, most antimicrobial packaging methods rely on inorganic chemicals that
are easily accessible. Concerns about potential responses or long-term impacts arise
when artificial chemical components are used in food processing. Incorporating bio-
active substances generated from natural sources can significantly enhance these
systems [171]. Smart packaging is a system that incorporates multiple types of tech-
nology. Despite their importance for food safety, the disposal phase of packaging is
complicated by monitoring and smart packaging technologies. Neither biodegrad-
able nor readily recyclable is the majority of the material used; in fact, many package
11 Smart Sensors for Quality Monitoring in Green Packaging Solutions 381
11.7 Conclusion
To boost food business profits, smart package solutions have been applied in recent
years. This is accomplished by minimizing food waste caused by improper storage
or handling and increasing the amount of time that food stays fresh. Additionally,
shoppers gain since their food will always be in the best possible state of freshness
and overall quality when they take it out of the package. Due to increased consumer
expectations and longer food supply chains brought about by globalization, retail
operations have been significantly impacted. These two forces have contributed to
the development of novel packaging technologies that aim to measure and optimize
the impact of various elements on food safety and quality, as well as to track the
food’s shelf life. The technology behind smart packaging is still in its early stages
of development, and there is a lot of room for additional commercial adoption. Put
another way, there still exists a technological chasm between what could be possible
and what could be commercially viable. The use of smart packaging is significant in
three ways. TTIs and similar tools do a great job of informing buyers about the quality,
microbiological safety, and freshness of food as well as its shelf life. Data systems like
barcodes and RFID tags also improve supply chain efficiency and effectiveness by
382 G. F. I. Toki et al.
Declaration The authors declare that they have no known competing financial interests or personal
relationships that could have appeared to influence the work reported in this paper. Generative AI
and AI-assisted technologies have been used in the writing process to improve the readability and
language of the work only. After using this tool, the author(s) reviewed and edited the content as
needed and take(s) full responsibility for the content of the publication.
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