Patil

Dr. Vikhe Patil Foundatlon's

Nikhe atil Aenorial Sehool, ute
TERM-I (2024-25)
STD: XII Subject: CHEMISTRY (Code:043) Maximum Marks: 70
Roll No.: Time Allowed:3 Hrs.
Date: 25 /09/2024 Number of Printed Pages :04
GENERAL INSTRUCTIONS:
A) There are 33questions in this question paper. Al questions are compulsory.
B) Section A: [Link]. I to 16 are objective type questions and carry l mark each.
C) Section B: Q. No. 17 to 21are short answer questions and carry 2marks each.
D) Section C: [Link]. 22 to 28 are short answer qucstions and carry 3marks cach.
E) Section D:Q. No. 29,30are case study-based questions and carry 4 marks each.
F) Section E: [Link].31,32 and 33 are long answer questions carrying 5marks each.
G) There is no overall choice. However, internal choices have been provided.

(SECTION-A)
[Link]. 1to 16 are objective type questions and carry 1 mark each.
Q1 The unit of ebulioScopic constant is
a) K Kg mol! b) KL mol-1
c)Kg mol-'K-1 d) K moiality
02 4L of 0.02 M aqueous solution of NaCl was diluted by adding one lit of water. The molality of the
resultant solution is ---
a) 0.004M b)0.008M
c) 0.012M d) 0.016M
Q3 The ANODE reaction during discharging of lead storage battery leads to the
a) formation of PbSO4 b)reduction of Pb* to Pb+
c) formation of Pb02 d) deposition of Pb at anode

Q4 Which of the following option will be the limiting molar conductivity of CH3COOHif the limiting
molar conductivity of CHSCOONa is 918cm mol. Limiting molar conductivity for individual ions
are

IONS Limiting molar conductivity

1 H+ 349.6

2 Nat 50.1

3 K+ 73.5

4 OH 199.1

a) 350 b) 375.3
c)390.5 d)340.4
Q5 For a reaction A+B> product; the rate law is given by r =K[A]"B]', what is the order of the
reaction?
a) 1/2 b)3/2
c) 2 d) 2.5
Q6 H,0, +[’H0+IO!
H,0, +I0-’H20 +['+O2
Both the reactions are biomolecular elementary reactions. The reaction intermediate is
a) H,0 b) IO1
c) d) O
Q7 Magnetic moment is calculated using the formula a=n(nt2),
Ti willhave magnetic moment
a)1.73 b)2.84
c)3.87 d) 4.90
 C H , - C B r - C H , - C H - C H z - C H , C I

Q8 The IUPAC name of the compound shown below is: 6-bromo-2-chlorohexene

a) 2-bromo-6-chlorohex-1-ene b) 5-bromo-1-chlorohex-5-ene

c) 3-bromo-1-chlorohexene d)
OR
CH;-CH(CH3)-CH-Br
Write IUPAC name of the following compound b)1-bromo-2-methylprop-1-ene

a) 3-Bromo-2-methylprop-1-ene
d)3-Bromo-propene
c) 2-methyl-1-bromopropene
09 Acidified permanganate solution oxidises oxalates to
b) Mn2+
a) Co
c) O2 d) CO
Q10 The ether

o-CH,
When treated with HI gives
a

-CHH
b

CH,OH

OH
d) Both a and c
ion in the following complex
Q11 The oxidation state and coordination number of the central metal
respectively is K3[Co(C04)3]
a) +3,6 b) +3,3
c) -3,3 d) 6,+3
magnetic moment value?
Q12 Amongst the following ions which one has the highest
a) [Cr(H20)6] 3+ b) [Fe(H,0)6| 2+
c) [Zn(H0)%12+ d) Fe(H20)6] 3+*
compounds: A, B, and C. Compounds A and B were
Q13 The Lucas test was carried out on three different
become turbid until it was heated.
turbid at ambient temperature, while compound Cdid not
structure?
Which one of the compounds is tertiary in
b)Cannot be determined
a) A
d) A and B
c) C
Which of the following processes does not result in
the production of alcohol?
Q14
hydration of alkenes
a) Acid catalysed b) Free radical halogenation of alkanes
c) Reduction of aldehydes d) Hydroboration-oxidation of alkenes
complex 0s:
Q15 Amongst the following, the most stable
a) [Ni (NH)6]* b) [Co(en)a]*
) [Fe (CN)j3 d) [Ni (Ha0).12+
2,4,6-trinitrophenol, 3-nitrophenol, 3,5
Q16 Which among the following is most acidic , Propan-1-ol,
dinitrophenol, phenol, 4-methylphenol.
b) 3,5-dinitrophenol,
a) 2,4,6-trinitrophenol
d) 4-methylphenol.
c) Propan-1-ol
(SECTION-B)
questions and carry 2 marks each.
Q. No. 17 to 21 are short anser It has a vapour
5g of non-volatile solute in 95g of water.
QI7 A solution was prepared by dissolving solute.
[Link] he molar mass of the
pressure of 23.375 mm Hg at K is 23..75 mm Hg)
water at 298
(Vapour pressure of pure
Q18 A copper-silver cellis set up. The copper ion concentration in it is 0.10 M. The concentration of
silver ion is not known, The cell potential is heasured 0,422 V. Determine the concentration of silver
ion in the cell.
Given : E°Agt/Ag =+0.80 V, E° 2/Cu =+0.34 V.
OR
When a certain conductance cell was filled wIth 0.1 M KC1, it has a resistance of 85 ohms at 25°C.
When the same cellwas filled with an aqueous solution of 0.052 M unknown electrolyte, the resistance
was 96 ohms. Calculate the molar conductanCe of the electrolyte at this concentration.
Specific conductance of 0.1 MKCl= 1.29 x 10* ohm:' cm-1
Q19 Give the IUPAC names of the following compounds:
H CH3
H
H3C H
H (ii) H
(i) Br -Br
H
H3C H3

Determine the amount of CaCl, (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure
Q20
is 0.75 atm at 27°C.
its reaction with: (i)
Q21 Describe the oxidising action of potassium dichromate and write the ionic equations for
iodide (ii) iron(|1) solution and (iii) H2S
(SECTION-C)
Q. No. 22 to 28 are short answer questions andcarry 3 marks each.
The electrical resistance of a column of 0.05 M NaOH solution of diameter 1 cm and length 50 cm
Q22
is 5.55x103 ohm. Calculate its resistivity, conductivity and molar conductivity.
Q23 A solution of Ni(NO3)2 is electrolysed between platinum electrodes using a current of 5 amperes
for 20 minutes. What mass of Ni is deposited at the cathode?( at [Link]-58.7g)
mol-1.
Q24 The molar conductivity of a1.5 M solution of an electrolyte is found to be 138.9 S cm2
Calculate the conductivity of this solution.
OR
reaction
The standard electrode potential (E°) for Daniel cell is +1.1 V. Calculate the AG° for the
Zn(s) + Cu(aq) ’ Zn(ag) + Cu(s) (F=96500 C mol).
Q25 A first order reaction takes 40 min for 30% decomposition. calculate t"(log 7-0.8450)
Q26 Write the equations involved in the following reactions:
i) Reimer - Tiemann reaction
(11) Kolbe's reaction
Write the reactions involved in the preparation of K2Cr207 from chromite ore (FeCr04).
Q27
OR
What is mischmetal? where it is used?
Q28 Explain giving reasons
a) Transition metals and many of their compounds show paramagnetic behaviour.
b) The enthalpies of atomization of the transition metals are high.
c) Zn, Cd and Hg are notconsidered as transition metals.
OR
How many geometrical isomers are possible in the following coordination entities?
(i) [Cr(C04):3] 3
(ii) [Co(NH3)3Cl3]
 (SECTION-D)
marks each.
Q. No. 29,30 are case study-based auestions and carry 4
Q29 Read the given passage and answer the questions,
relative to the total number of
Colligative properties depend on the number of solute particles
independent of identity of the solute particles.
particles present in the solution. These properties are
The Examples of colligative properties are
1) Relative lowering of vapour pressure of the solvent
2) Depression in freezing point of the solvent
3) Elevation in boiling point of the solvent.
4) Osmotic pressure of the solution. into it?
decrease when a non-volatile solute is added
A. Why does vapour pressure of a liquid
order of van't Hoff factor
B. Arrange the following in increasing
0.1m CaCl2,0.1 M KCI,0.1 MAl(SO4)3.0.1 M C12H22011
Explain.
chloride and sodium sulphate are not isotonic.
C. Equimolar aqueous solution of sodium
are
D. The value of van't Hoff factor for KCI and KS04
or group of atoms which can donate a pair of electrons to vacant orbital
Q30 Ligand is an ion or an atom the central atom or
metal ion or atom. Any molecule or ion which can form coordinate bond with
of metal atom using
compound, Unidentate ligand bonds to a
ion will act as ligand in a coordination through two donor
Didentate ligand bonds to a metal ion
an electron pair of a single donor atom. donor atoms.
atoms. Ambidentate ligand can bond to
a metal through either of two different
(C04)
a) What is the name of the bidentate ligand
b) What the coordination number of Co, (NH4)2[CoF4]
in
c) Give one example of each
1) Neutral ligand of carbon
2) Ambidentate ligand

(SECTION-E)
questions carrying 5 marks each.
[Link].31,32 and 33 are long answer

reactions:
organic product in each of the following
Q31 Write the structure of the major
CH3CHCH, Cl + Nal
(i)
(CH3)3CBr + KOH
(ii) CH;CH(Br)CH;CH; + NaOH
(ii)
CH;CH,Br + KCN
(iv)
CoHsONa + CzHsCI
(v)
OR

What happenswhen
alcoholic KOH,
() n-butyl chloride is treated with
bromobenzene is treated with Mg in
the presence of dry ether,
(ii
(ii) chlorobenzene is subjected to hydrolysis,
aqueous KOH,
(iv) ethylchloride is treated with
methyl bromide is treated with sodium
in the presence of dry ether,
(V) out?
Q32 How are the following conyersions carried
() Propene ’ Propan-2-ol.
() Benzyl chloride Benzyl alcohol.
Propan-l-ol.
(ii) Ethyl magnesium chloride 2-Methylpropan-2-ol.
(iv) Methyl magnesium bromide ’
(v) Phenolbenzene

Q33 reaction.
a first order
rate equation for rate constant of the reaction.
decomposition. Calculate t12 for
a) Derive integrated
takes 10 minutes for 25%
b) A first order reaction =0.4771, log 4=0.6021).
(Given: log 2 = 0.3010, log 3